Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-25T00:35:24.827Z Has data issue: false hasContentIssue false
  • English
  • Français

High-resolution and Precisely dated record of weathering and hydrological dynamics recorded by manganese and rare-earth elements in a stalagmite from Central China

Published online by Cambridge University Press:  20 January 2017

Houyun Zhou ,
Baoquan Chi ,
Michael Lawrence ,
Jianxin Zhao ,
Jun Yan ,
Alan Greig  and
Yuexing Feng
Houyun Zhou*
Affiliation:
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan, Guangzhou 510640, China
Baoquan Chi
Affiliation:
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan, Guangzhou 510640, China
Michael Lawrence
Affiliation:
Radiogenic Isotope Laboratory, Centre for Microscopy and Microanalysis, the University of Queensland, Brisbane, Queensland 4072, Australia
Jianxin Zhao
Affiliation:
Radiogenic Isotope Laboratory, Centre for Microscopy and Microanalysis, the University of Queensland, Brisbane, Queensland 4072, Australia
Jun Yan
Affiliation:
School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China
Alan Greig
Affiliation:
School of Earth Sciences, University of Melbourne, Melbourne, 3010, Australia
Yuexing Feng
Affiliation:
Radiogenic Isotope Laboratory, Centre for Microscopy and Microanalysis, the University of Queensland, Brisbane, Queensland 4072, Australia
*
*Corresponding author. Fax: +86 20 85290130.E-mail address:[email protected] (H. Zhou).
Get access Rights & Permissions [Opens in a new window]

Abstract

Manganese (Mn) and rare-earth elements (REEs) in a stalagmite (SJ3) collected from Central China were analyzed, using an ICP-MS method for the precise determination of > 40 trace elements in geological samples by enriched-isotope internal standardization. Unlike speleothem Mn and REEs investigated by cathodoluminescence, which may be incorporated into crystal lattice, the Mn and REEs analyzed in SJ3 should come largely from colloidal and particle phases in groundwater and may be associated with non-carbonate inclusions. The Mn and REEs in SJ3 vary significantly during the period between 20 and 10 ka. These elements show remarkable increases since ∼ 14.5 ka, suggesting enhanced weathering of the overlying soil layer and the host rock since the onset of the last deglaciation and the strengthening of the Asian summer monsoon. In addition, the Mn and REEs in SJ3 display significant centennial fluctuations which may reflect groundwater dynamics.

Keywords

MnREEsSpeleothemWeatheringHydrologyEast AsiaSummer monsoon
Type
Original Articles
Information
Quaternary Research , Volume 69 , Issue 3 , May 2008 , pp. 438 - 446
Copyright
University of Washington

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

An, Z.S., (2000). The history and variability of the East Asian paleomonsoon climate. Quaternary Science Reviews 19, 171–187.Google Scholar
Baker, A., Ito, E., Smart, P.L., McEwan, R.F., (1997). Elevated and variable values of C-13 in speleothems in a British cave system. Chemical Geology 136, 263–270.Google Scholar
Banner, J.L., Musgrove, M., Asmerom, Y., (1996). High-resolution temporal record of Holocene ground-water chemistry: tracing links between climate and hydrology. Geology 24, 1049–1052.Google Scholar
Bar-Matthews, M., Ayalon, A., Kaufman, A., (1999). The Eastern Mediterranean paleoclimate as a reflection of regional events: Sore Qcave, Israel. Earth and Planetary Science Letters 166, 85–95.Google Scholar
Baskaran, M., Krishnamurthy, R.V., (1993). Speleothems as proxy for the carbon isotope composition of atmospheric CO2. Geophysical Research Letters 20, 2905–2908.Google Scholar
Bureau of Geology and Mineral Resources of Sichuan Province, , (1991). Regional Geology of Sichuan Province. Geological Publishing House, Beijing., .Google Scholar
Brookins, D.G., (1989). Aqueous geochemistry of rare earth elements. Lipin, B.R., Mckay, G.A., Geochemistry and Mineralogy of Rare Earth Elements. Mineralogical Society of America, Washington D. C.., 200–225.Google Scholar
Ding, Z.L., Sun, J.M., Liu, T.S., Zhu, R.X., Yang, S.L., Guo, B., (1998). Wind-blown origin of the Pliocene red clay formation in the central Loess Plateau, China. Earth and Planetary Science Letters 161, 135–143.Google Scholar
Dorale, J.A., Edwards, R.L., Ito, E., Gonzàlez, L.A., (1998). Climate and vegetation history of the midcontinent from 75 to 25 ka: a speleothem record from Crevice Cave, Missouri, USA. Science 282, 1871–1874.Google Scholar
Dykoski, C.A., Edwards, R.L., Cheng, H., Yuan, D., Cai, Y., Zhang, M., Lin, Y., Qin, J., An, Z., Revenauh, J., (2005). A high-resolution, absolute-dated Holocene and deglacial Asian monsoon record from Dongge Cave, China. Earth and Planetary Science Letters 233, 71–86.CrossRefGoogle Scholar
Edwards, R.L., Chen, J.H., Wasserburg, G.J., (1987). 238U-234U-230Th-232Th systematics and the precise measurement of time over the past 500,000 years. Earth and Planetary Science Letters 81, 175–192.Google Scholar
Eggins, S.M., Woodhead, J.D., Kinsley, L.P.J., (1997). A simple method for the precise determination of > 40 trace elements in geological samples by ICPMS using enriched isotope internal standardisation. Chemical Geology 134, 311–326.Google Scholar
Fairchild, I.J., Baker, A., Borsato, A., Frisia, S., Hinton, R.W., McDermott, F., Tooth, A.F., (2001). High-resolution, multiple trace-element variation in speleothems. Journal of the Geological Society 158, 831–841.Google Scholar
Fairchild, I.J., Smith, C.L., Baker, A., Fuller, L., Spötl, C., Mattey, D., McDermott, F., E.I.M.F., , (2006). Modification and preservation of environmental signals in speleothems. Earth-Science Reviews 75, 105–153.Google Scholar
Fang, X.M., Li, J.J., Van der Voo, R., (1999). Age and provenance of loess in West Qinling, Chinese. Science Bulletin 44, 23, 2188–2192.Google Scholar
Fleet, A.J., (1984). Aqueous and sedimentary geochemistry of rare earth elements. Henderson, J., Rare Earth Element Geochemistry. Elsevier, Amsterdam., 343–373.Google Scholar
Frumkin, A., Stein, M., (2004). The Sahara-East Mediterranean dust and climate connection revealed by strontium and uranium isotopes in a Jerusalem speleothem. Earth and Planetary Science Letters 217, 451–464.Google Scholar
Gaft, M., Reisfeld, R., Panczer, G., (2005). Luminescence spectroscopy of minerals and materials. Springer 119–168, 200–209.Google Scholar
Gallet, S., Jahn, B.M., Torii, M., (1996). Geochemical characterization of loess–paleosol sequence from the Luochuan section, China and its paleoclimatic implications. Chemical Geology 133, 67–88.Google Scholar
Genty, D., Blamart, D., Ouahdi, R., Gilmour, M., Baker, A., Jouzel, J., van Exter, S., (2003). Precise dating of Dansgaard–Oeschger climate oscillations in western Europe from stalagmite data. Nature 421, 833–837.Google Scholar
Goede, A., McCulloch, M., McDermott, F., (1998). Aeolian contribution to strontium and strontium isotope variations in a Tasmanian speleothem. Chemical Geology 149, 37–50.Google Scholar
Grootes, P.M., Stuiver, M., White, J.W.C., Johnsen, S., Jouzel, J.J., (1993). Comparison of oxygen isotope records from the GISP2 and GRIP Greenland ice cores. Nature 366, 552–554.Google Scholar
Holmgren, K., Karlén, W., Shaw, P.A., (1995). Paleoclimatic significance of the stable isotopic composition and petrology of a late Pleistocene stalagmite from Botswana. Quaternary Research 43, 320–328.Google Scholar
Hu, C.-Y., Huang, J.-H., Fang, N.-Q., (2005). Adsorbed silica in stalagmite carbonate and its relationship to past rainfall. Geochimica et Cosmochimica Acta 69, 2285–2292.Google Scholar
Huang, Y.M., Fairchild, I.J., Borsato, A., Frisia, S., Cassidy, N.J., McDermott, F., Hawkesworth, C.J., (2001). Seasonal variations in Sr, Mg and P in modern speleothems (Grotta di Ernesto, Italy). Chemical Geology 175, 429–448.Google Scholar
Ji, H.B., Wang, S.J., Ouyang, Z.Y., Zhang, S., Sun, C.X., (2004). Geochemistry of red residua underlying dolomites in karst terrains of Yunnan–Guizhou Plateau II. The mobility of rare earth elements during weathering. Chemical Geology 203, 29–50.Google Scholar
Kamber, B.S., Greig, A., Schoenberg, R., Collerson, K.D., (2003). A refined solution to Earth's hidden niobium: implications for evolution of continental crust and mode of core formation. Precambrian Research 126, 289–308.
Kaufman, A., Wasserburg, G.J., Porcelli, D., (1998). U-Th isotope systematics from the Soreq cave, Israel and climatic correlations. Earth and Planetary Science Letters 156, 141–155.Google Scholar
Lawrence, M.G., Greig, A., Collerson, K.D., Kamber, B.S., (2006). Rare earth element and yttrium variability in South East Queensland waterways. Aquatic Geochemistry 12, 39–72.CrossRefGoogle Scholar
Lei, X.Y., Yue, L.P., Wang, J.Q., (1998). Magnetic characteristics and their paleoclimatic significance of Fengzhou loess in the Qinling Mountains of China. Chinese Science Bullettin 43, 1571–1575.Google Scholar
Li, H.-C., Ku, T.-L., You, C.-F., (2005). 87Sr/86Sr and Sr/Ca in speleothems for paleoclimate reconstruction in Central China between 70 and 280 kyr ago. Geochimica et Cosmochimica Acta 69, 3933–3947.CrossRefGoogle Scholar
Liu, T.S., (1985). Loess and Environment. China Ocean Press, Beijing., 1–234.Google Scholar
McCarthy, J.F., Sanford, W.E., Stafford, P.L., (1998). Lanthanide field tracers demonstrate enhanced transport of transuranic radionuclides by natural organic matter. Environmental Science & Technology 32, 3901–3906.Google Scholar
McDermott, F., (2004). Palaeo-climate reconstruction from stable isotope variations in speleothems: a review. Quaternary Science Reviews 23, 901–918.Google Scholar
McLennan, S.M., (1989). Rare earth elements in sedimentary rocks: influence of province and sedimentary processes. Lipin, B.R., Mckay, G.A., Geochemistry and Mineralogy of Rare Earth Elements. Mineralogical Society of America, Washington D.C.., 169–200.Google Scholar
Mickler, P.J., Banner, J.L., Stern, L., Asmerom, Y., Edwards, R.L., Ito, E., (2004). Stable isotope variations in modern tropical speleothems: evaluating applications to paleoenvironmental reconstructions. Geochimica et Cosmochimica Acta 68, 4381–4393.Google Scholar
Middelburg, J.J., van der Weijden, C.H., Woittiez, J.R.W., (1988). Chemical processes affecting the mobility of major, minor and trace elements during weathering of granitic rocks. Chemical Geology 68, 2253–2273.Google Scholar
Musgrove, M., Banner, J.L., Mack, L.E., Combs, D.M., James, E.W., Cheng, H., Edwards, R.L., (2001). Geochronology of late Pleistocene to Holocene speleothems from Central Texas: implications for regional paleoclimate. Geological Society of America Bulletin 113, 1532–1543.Google Scholar
Nesbitt, H.W., (1979). Mobility and fractionation of rare earth elements during weathering of a granodiorite. Nature 279, 206–210.CrossRefGoogle Scholar
Palmer, M.R., (1985). Rare earth elements in foraminifera tests. Earth and Planetary Science Letters 73, 285–298.Google Scholar
Richter, D.K., Götte, T., Niggemann, S., Wurth, G., (2004). REE3+ and Mn2+ activated cathodoluminescence in lateglacial and Holocene stalagmites of central Europe: evidence for climatic processes?. The Holocene 14, 759–767.Google Scholar
Roberts, M.S., Smart, P., Baker, A., (1998). Annual trace element variations in a Holocene speleothem. Earth and Planetary Science Letters 154, 237–246.Google Scholar
Samadi, A., Gilkes, R.J., (1998). Forms of phosphorus in virgin and fertilised calcareous soils of Western Australia. Australian Journal of Soil Research 36, 585–601.Google Scholar
Sholkovitz, E.R., William, M.L., Lewis, B.L., (1994). Ocean particle chemistry: the fractionation of rare earth elements between suspended particles and seawater. Geochimica et Cosmochimica Acta 58, 1567–1579.Google Scholar
Spötl, C., Fairchild, I.J., Tooth, A.F., (2005). Cave air control on dripwater geochemistry, Obir Caves (Austria): implications for speleothem deposition in dynamically ventilated caves. Geochimica et Cosmochimica Acta 69, 2451–2468.Google Scholar
Stuiver, M., Grootes, P.M., Braziunas, T.F., (1995). The GISP2 delta 18O climate record of the past 16,500 years and the role of the sun, ocean, and volcanoes. Quaternary Research 44, 341–354.CrossRefGoogle Scholar
Veizer, J., (1983). Chemical diagenesis of carbonates: theory and application of trace element technique. Arthur, M.A., Stable Isotopes in Sedimentary Geology, SEPM Short Course, no. 10.Google Scholar
Wang, Y.J., Cheng, H., Edwards, R.L., (2001). A high-resolution absolute-dated Late Pleistocene monsoon record from Hulu Cave, China. Science 294, 2345–2348.Google Scholar
Wang, X.F., Auler, A.S., Edwards, R.L., Cheng, H., (2004). Wet periods in northeastern Brazil over the past 210 kyr linked to distant climate anomalies. Nature 432, 740–743.Google Scholar
Yuan, D.X., Cheng, H., Edwards, R.L., (2004). Timing, duration, and transitions of the last interglacial Asian monsoon. Science 304, 575–578.Google Scholar
Zhao, J.X., Hu, K., Collerson, K.D., (2001). Thermal ionization mass spectrometry U-series dating of a hominid site near Nanjing, China. Geology 29, 27–30.Google Scholar
Zhou, J.Z., Lundstrom, C.C., Fouke, B., (2005). Geochemistry of speleothem records from southern Illinois: development of 234U/238U as a proxy for paleoprecipitation. Chemical Geology 221, 1–20.Google Scholar
Zhou, H.Y., Zhao, J.X., Feng, Y.X., Gagan, M.K., Zhou, G.Q., Yan, J., in press, Synchronous and distinct heinrich event one in Central and East China recorded by stable oxygen and carbon isotopic compositions in stalagmites from China. Quat. Res. doi:10.1016/j.yqres.2007.11.001.Google Scholar
Zhou, H.Y., Li, T.G., Jia, G.D., Zhu, Z.Y., Chi, B.Q., (2007). Sea surface temperature reconstruction for the Middle Okinawa Trough during the Last Glacial-Interglacial Cycle using C37 unsaturated alkenones. Palaeogeography, Palaeoclimatology, Palaeoecology 240, 440–453.Google Scholar