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Mineralogic and Climatic Interpretations of the Luochuan Loess Section (China) Based on Diffuse Reflectance Spectrophotometry

Published online by Cambridge University Press:  20 January 2017

Junfeng Ji
Affiliation:
Institute of Surface Geochemistry, State Key Laboratory of Mineral Deposit Research, Department of Earth Sciences, Nanjing University, Nanjing, 210093, China
William Balsam
Affiliation:
Department of Geology, University of Texas at Arlington, Arlington, Texas, 76019
Jun Chen
Affiliation:
Institute of Surface Geochemistry, State Key Laboratory of Mineral Deposit Research, Department of Earth Sciences, Nanjing University, Nanjing, 210093, China

Abstract

We examined the top 135 m, that is, the entire Pleistocene, of the classic Luochuan section on the Chinese Loess Plateau with a diffuse reflectance spectrophotometer from the near ultraviolet, through the visible, and into the near infrared. From the reflectance data we calculated sample brightness which, with some caveats, is a reasonable proxy for magnetic susceptibility. Mineralogic changes were identified by factor analyzing the first derivative of the percent reflectance data and examining samples with high factor scores. Two factors which explain about 96% of the cumulative variance are distinguished by the relative proportion of hematite and goethite, the minerals that are responsible for the color changes in the loess sequence. Both hematite and goethite are present in both loess and paleosol but goethite dominates in loess whereas hematite dominates in paleosol. The goethite factor exhibits an inverse correlation with magnetic susceptibility; the hematite factor exhibits a weak positive correlation with susceptibility. Paleoclimatic interpretations are drawn from comparison of susceptibility to the concentration of spectrally identified hematite. Based on this comparison, paleosols in the early Pleistocene Wucheng Formation are characterized by conditions that are drier than today, a “dry summer monsoon”, whereas later Pleistocene paleosols are characterized by a “wet summer monsoon”.

Type
Research Article
Copyright
University of Washington

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References

An, Z.S., Liu, T.S., Lou, Y.C., Porter, S.C., Kukla, G., Wu, X.H., and Hua, Y.M. (1990). The long-term paleomonsoon variation recorded by the loess-palaeosol sequence in central China. Quaternary International 7/8, 9195.Google Scholar
An, Z.S., Kukla, G., Porter, S.C., and Xiao, J.L. (1991). Magnetic susceptibility evidence of monsoon variation on the Loess Plateau of central China during the last 130,000 years. Quaternary Research 36, 2936.CrossRefGoogle Scholar
Balsam, W.L., and Deaton, B.C. (1991). Sediment dispersal in the Atlantic Ocean: Evaluation by visible light spectra. Reviews in Aquatic Sciences 4, 411447.Google Scholar
Balsam, W.L., and Damuth, J.E. (2000). Further investigations of shipboard vs shore-based spectral data: Implications for interpreting Leg 164 sediment composition. Ocean Drilling Program Science Volume 164s, 313324.Google Scholar
Balsam, W.L., Damuth, J.E., and Schneider, R.R. (1997). Comparison of shipboard vs. shore-based spectral data from Amazon Fan cores: Implications for interpreting sediment composition. Ocean Drilling Program Science Volume 155s, 193215.Google Scholar
Balsam, W.L., Deaton, B.C., and Damuth, J.E. (1999). Evaluating optical lightness as a proxy for carbonate content in marine sediment cores: Implications for marine sedimentation. Marine Geology 161, 141153.CrossRefGoogle Scholar
Bronger, A., and Heinkele, T.H. (1989). Micromorphology and genesis of paleosols in the Luochuan loess section, China: Pedostratigraphic and environmental implications. Geoderma 45, 123143.CrossRefGoogle Scholar
Chen, J., An, Z.S., and Head, J. (1999). Variation in Rb/Sr ratios in the loess-paleosol sequence of central China during the last 130,000 years and their implication for monsoon paleoclimatology. Quaternary Research 51, 215219.CrossRefGoogle Scholar
Chen, J., Wang, Y., Chen, Y., Liu, L., Ji, J., and Lu, H. (2000). Rb and Sr geochemical characterization of the Chinese loess stratigraphy and its implications for paleomonsoon climate. Journal of the Geological Society of China 74, 279288.Google Scholar
Deaton, B.C., and Balsam, W.L. (1991). Visible spectroscopy—A rapid method for determining hematite and goethite concentration in geological materials. Journal of Sedimentary Petrology 61, 628632.CrossRefGoogle Scholar
Ding, Z.L., Yu, Z.W., Rutter, N.W., and Liu, T.S. (1994). Towards an orbital time scale for Chinese loess deposits. Quaternary Science Reviews 13, 3970.CrossRefGoogle Scholar
Evans, M.E., and Heller, F. (1994). Magnetic enhancement and paleoclimate: Study of a loess/paleosol couplet across the Loess Plateau of China. Geophysical Journal International 117, 257264.CrossRefGoogle Scholar
Fine, P., Verosub, K.L., and Singer, M.J. (1995). Pedogenic and lithogenic contributions to the magnetic susceptibility record of the Chinese loess/palaeosol sequence. Geophysical Journal International 122, 97107.CrossRefGoogle Scholar
Guo, Z.T., Liu, T.S., Fedoff, N., Weir, L.Y., Ding, Z.L., Wu, N.Q., Lu, H.Y., Jiang, W.Y., and An, Z.L. (1998). Climate extremes in loess of China coupled with the strength of deep water formation in the North Atlantic. Global Planetary Change 18, 113128.CrossRefGoogle Scholar
Heller, F., and Liu, T.S. (1984). Magnetism of Chinese loess deposits. Geophysical Journal of the Royal Astronomical Society 77, 125141.CrossRefGoogle Scholar
Heller, F., and Liu, T.S. (1986). Paleoclimatic and sedimentary history from magnetic susceptibility of loess in China. Geophysical Research Letters 13, 11691172.CrossRefGoogle Scholar
Hunt, C.P., Banerjee, S.K., Han, J., Solheid, P.A., Oches, E., Sun, W., and Liu, T. (1995). Rock-magnetic proxies of climate changes in the loess-paleosol sequences of the western Loess Plateau of China. Geophysical Journal International 123, 232244.CrossRefGoogle Scholar
Kukla, G. (1987). Pleistocene climates in China dated by magnetic susceptibility. Quaternary Science Review 6, 191219.CrossRefGoogle Scholar
Kukla, G., and An, Z.S. (1989). Loess stratigraphy in central China. Palaeogeography, Palaeoclimatology, Palaeoecology 72, 203225.CrossRefGoogle Scholar
Kukla, G., Heller, F., Liu, X., Xu, T.C., Liu, T.S., and An, Z.S. (1988). Pleistocene climates dated by magnetic susceptibility. Geology 16, 811814.2.3.CO;2>CrossRefGoogle Scholar
Liu, T.S., and Ding, Z.L. (1998). Chinese loess and the paleomonsoon. Annual Review of Earth and Planetary Sciences 26, 111145.CrossRefGoogle Scholar
Liu, T.S. (1985). Loess and Environment. China Ocean Press, Beijing.Google Scholar
Liu, X.M., Hesse, P., and Rolph, T. (1999). Origin of maghemite in Chinese loess deposits: Aeolian or pedogenic. Physics of the Earth and Planetary Interiors 112, 191201.CrossRefGoogle Scholar
Lu, H., Liu, X., Zhang, F., An, Z., and Dodson, J. (1999). Astronomical calibration of loess-paleosol deposits at Luochuan, central Chinese Loess Plateau. Palaeogeography, Palaeoclimatology, Palaeoecology 154, 237246.CrossRefGoogle Scholar
Maher, B.A. (1998). Magnetic properties of modern soils and Quaternary loessic paleosols: Paleoclimatic implications. Palaeogeography, Palaeoclimatology, Palaeoecology 137, 2554.CrossRefGoogle Scholar
Maher, B.A., and Thompson, R. (1991). Mineral magnetic record of the Chinese loess and paleosols. Geology 19, 36.2.3.CO;2>CrossRefGoogle Scholar
Maher, B.A., and Thompson, R. Paleomonsoons I: The magnetic record of paleoclimate in the terrestrial loess and paleosol sequences. Maher, B.A., and Thompson, R. (1999). Quaternary Climates, Environments and Magnetism. Cambridge Univ. Press, Cambridge. 81125.Google Scholar
Porter, S. (2000). High-resolution paleoclimatic information from the Chinese eolian sediments based on grayscale intensity profiles. Quaternary Research 53, 7077.CrossRefGoogle Scholar
Porter, S.C., and An, Z.S. (1995). Correlation between climate events in the North Atlantic and China during the last glaciation. Nature 375, 305308.CrossRefGoogle Scholar
Schwertmann, U., and Murad, E. (1983). Effect of pH on formation of goethite and hematite from ferrihydrite. Clays and Clay Minerals 31, 277284.CrossRefGoogle Scholar
Schwertmann, U., and Taylor, R.M. Iron oxides. Dixon, J.B., and Weed, S.B. (1989). Minerals in Soil Environments. Soil Society of America, Madison. 379438.Google Scholar
Tite, M.S., and Linington, R.E. (1975). Effect of climate on the magnetic susceptibility of soils. Nature 265, 565566.CrossRefGoogle Scholar
Zhou, L.P., and Shackleton, N.J. (1998). Loess spectrophotometry: A tool for detecting climate-related events. Past Global Changes and Their Significance for the Future. p. 139 Google Scholar
Zhou, L.P., Oldfield, F., and Wintle, A.G. (1990). Partly pedogenic origin of magnetic variations in Chinese loess. Nature 346, 737739.CrossRefGoogle Scholar