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XVII.—The Explanation of an apparent Anomaly outstanding in the Results of Measurement of Dissociation Pressures
Published online by Cambridge University Press: 15 September 2014
Extract
In 1888 Tammann, applying a form of the gas current saturation method to the measurement of the dissociation pressures of salt hydrates, obtained results which were uniformly higher by from 2 to 5 per cent, than the results obtained by Frowein with the tensimeter. This anomalous behaviour was confirmed, in Nernst's laboratory, by Schottky, who reported that the initial dissociation pressures developed in tensimetric measurements were, in cited cases, higher than the equilibrium values. In 1911 Partington, re-studying certain of the facts, added further confirmation by the use of the gas current saturation method in a somewhat altered form.
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References
page 158 note * Ann. Physik, xxxiii, p. 322 (1888).
page 158 note † Z. physik. Chem., i, p. 5 (1887).
page 158 note ‡ Z. physik. Chem., lxiv, p. 415 (1908).
page 158 note § J. Chem. Soc., xcix, p. 466 (1911).
page 158 note ∥ Z. physik. Chem., lxiv, p. 415 (1908).
page 158 note ¶ Ann. Rep. Progress Chem., viii, p. 34 (1912).
page 158 note ** Trans. Faraday Soc., x, p. 195 (1914).
page 159 note * Cf. Menzies, J. Amer. Chem. Soc., xlii, p. 978 (1920).
page 159 note † Trans. Roy. Soc. London, A, ccix, p. 177 (1909).
page 159 note ‡ The matter will be referred to elsewhere.
page 159 note § Cf. Menzies, loc. cit.
page 160 note * Nature, xcv, p. 34 (1915).