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Synthesis by Means of Electrolysis.—Part III. Synthesis of n-Dicarbodecahexanic Acid

Published online by Cambridge University Press:  15 September 2014

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(abstract)

The synthesis of the diethyl ether of this new acid was effected by the electrolysis of a strong aqueous solution of potassium ethyl sebate, COOC2H6(CH2)8COOK. This salt was prepared by adding the calculated quantity of alcoholic potash to an alcoholic solution of diethyl sebate. After some time the potassium ethyl salt began to separate out: the whole was then boiled, allowed to cool, and filtered. What remained on the filter was dissolved in water; the aqueous solution was extracted twice with ether, and then evaporated to a concentration suitable for electrolysis (cf. this vol. p. 54).

Type
Proceedings 1889-90
Copyright
Copyright © Royal Society of Edinburgh 1891

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