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Synthesis by Means of Electrolysis

Published online by Cambridge University Press:  15 September 2014

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Abstract

Synthesis of Tetramethylsuccinic Acid.–Ethyl-potassium dimethylmalonate cannot be prepared from dimethylmalonic ether by following precisely the method which succeeded in all previous cases. When the ether is mixed, either at once or slowly, with the calculated quantity of caustic potash in alcoholic solution, half of the ether is completely saponified, while the other half is unacted on, only an insignificant fraction being half-saponified and converted into the ethyl-potassium salt. A good yield of the latter was, however, obtained by a modification of the process, the special points of which were great dilution with alcohol and low temperature

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1893

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References

* Fittig and Engelhorn, Liebig's Annalen 200, 70.

Fittig and Howe, Liebig's Annalen 200, 23.

Liebig's Annalen 200, 35.

note * page 248 Beriehte der deutschen chemischen Gessellschaft 24, 127.