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IX.—A Quantitative Study of the Constitution of Calomel Vapour

Published online by Cambridge University Press:  15 September 2014

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Extract

The vapour density of calomel vapour corresponds to the formula HgCl or Hg + HgCl2. Odling showed, by amalgamation of gold-leaf, the presence of free mercury. Harris and V. Meyer separated mercury from the vapour by diffusion, and also showed that solid potassium hydroxide turned yellow (HgO) when plunged into the vapour. Diffusion might naturally increase the dissociation, and even a pure mercurous salt would certainly give mercuric oxide at 240–260°, since at that temperature mercurous oxide is unstable. The quantitative conclusion of these observers, namely, that the vapour is completely dissociated, therefore, was not in any way justified by their qualitative experiments, although it has been accepted by many chemists.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1912

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References

page 183 note * J. Chem. Soc., iii. 211

page 183 note † Berichte, xxvii., 1842

page 184 note * Proceedings, xxx. 52

page 184 note † Proceedings, xxx. 521

page 185 note * Proceedings, vol. xxx. p.437