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1. On the Action of the Dry Gases on Organic Colouring Matters, and its relation to the Theory of Bleaching

Published online by Cambridge University Press:  16 March 2015

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Extract

This communication is divided into six sections. In the first, the author states that the object of his paper is to supply a defect in the theory of chlorine-bleaching, by endeavouring to explain why the removal of water from that gas arrests its bleaching action. In the preliminary discussion, he refers at some length to Davy's theory, that moist chlorine does not bleach directly, but only in a secondary way, by combining with the hydrogen of the associated water, and liberating the oxygen, which is the true bleacher. After pointing out the untenable assumptions and self-destructive arguments on which this theory is built, the author proceeds in the second section, which discusses the influence of sunlight on the bleaching action of dry chlorine, to shew; that Davy's proposition that dry chlorine does not bleach dry organic colours is true, provided direct sunlight be excluded, but does not apply to the gas when exposed to the actinic influence of the sunbeam. In a comparative trial, one specimen of dry litmus paper was found to resist the decolorizing action of dry chlorine for more than eight months when kept in darkness; whilst the colour of another portion of the same paper totally disappeared after six weeks' exposure to sunshine.

Type
Proceedings 1847-48
Copyright
Copyright © Royal Society of Edinburgh 1850

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