Emission lines from CO and Hi are the standard tracers of molecular and atomic interstellar medium, respectively. In the past two decades, a consensus has formed that a substantial fraction of Galactic molecular gas evades detection by these two tracers, thus giving rise to the empirical concept of dark molecular gas (DMG). Largely based on the experience and evidence garnered from the Arecibo Millennium survey, we have formed an international consortium, the Pacific Rim Interstellar Matter Observers (PRIMO), to pursue alternative tracers of DMG, particularly absorption against background radio sources (quasars). PRIMO have carried out observing programs at Arecibo, JVLA, Delingha 13.7m, ATCA and ALMA, among others. Our observations reveal abundant hydrides, namely OH and CH, in DMG clouds. The historical difficulty of mapping OH can be explained by the measured OH excitation temperature $f(T_{{\rm{ex}}}^{{\rm{OH}}}) \propto \frac{1}{{\sqrt {2\pi } \sigma }}{\rm{exp}}[ - {(ln(T_{ex}^{OH}) - ln(3.4\;K))^2}/(2{\sigma ^2})],$

which is a modified log-normal function peaking close to the numerical value of the L-band Galactic continuum background (synchrotron + CMB). Both OH and CH are shown to be better tracers of molecular hydrogen than CO, particularly in the intermediate extinction regions (Av ~ 0.05-2 magnitude), where DMG dominates. http://ism.bao.ac.cn/primo