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Observational Constraints for Modeling Diffuse Molecular Clouds

Published online by Cambridge University Press:  21 February 2014

S. R. Federman
S. R. Federman*
Affiliation:
Department of Physics and Astronomy, University of Toledo, MS 111, Toledo, 43606 OHUSA email: [email protected]
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Abstract

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Ground-based and space-borne observations of diffuse molecular clouds suggest a number of areas where further improvements to modeling efforts is warranted. I will highlight those that have the widest applicability. The range in CO fractionation caused by selective isotope photodissociation, in particular the large 12C16O/13C16O ratios observed toward stars in Ophiuchus, is not reproduced well by current models. Our ongoing laboratory measurements of oscillator strengths and predissociation rates for Rydberg transitions in CO isotopologues may help clarify the situtation. The CH+ abundance continues to draw attention. Small scale structure seen toward ζ Per may provide additional constraints on the possible synthesis routes. The connection between results from optical transitions and those from radio and sub-millimeter wave transitions requires further effort. A study of OH+ and OH toward background stars reveals that these species favor different environments. This brings to focus the need to model each cloud along the line of sight separately, and to allow the physical conditions to vary within an individual cloud, in order to gain further insight into the chemistry. Now that an extensive set of data on molecular excitation is available, the models should seek to reproduce these data to place further constraints on the modeling results.

Keywords

ISM: abundancesISM: moleculesastrochemistry
Type
Contributed Papers
Information
Proceedings of the International Astronomical Union , Volume 9 , Symposium S297: The Diffuse Interstellar Bands , May 2013 , pp. 321 - 329
Copyright
Copyright © International Astronomical Union 2014 

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