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Dissociative Recombination of CD3OD2+
Published online by Cambridge University Press: 21 March 2006
Abstract
The branching ratios of the different reaction pathways and the overall rate of the dissociative recombination of CD$_{3}$OD$_{2}^{+}$ were measured at the CRYRING storage ring located at the Manne Siegbahn Laboratory in Stockholm, Sweden. A preliminary analysis of the data yielded that formation of methanol accounts for only 6 $\pm$ 2% of the total reaction rate. Largely, dissociative recombination of CD$_{3}$OD$_{2}^{+}$ involves fragmentation of the C–O bond, the major process being the three-body break-up forming CD$_{3}$, OD and D (branching ratio 0.59). A non-negligible formation of interstellar methanol by the previously proposed mechanism is therefore very unlikely.
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- Contributed Papers
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- Proceedings of the International Astronomical Union , Volume 1 , Symposium S231: Astrochemistry: Recent Successes and Current Challenges , August 2005 , pp. 117 - 124
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- 2006 International Astronomical Union
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