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X-ray powder diffraction data for the ternary phases W5As2.5P1.5 and Ni4Nb5P4

Published online by Cambridge University Press:  10 January 2013

P. Bénard-Rocherullé ,
S. Députier ,
F. Charki  and
R. Guérin
P. Bénard-Rocherullé*
Affiliation:
Université de Rennes I, Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS-Université No. 6511, Avenue du Général Leclerc, 35042 Rennes Cedex, France
S. Députier
Affiliation:
Université de Rennes I, Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS-Université No. 6511, Avenue du Général Leclerc, 35042 Rennes Cedex, France
F. Charki
Affiliation:
Université de Rennes I, Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS-Université No. 6511, Avenue du Général Leclerc, 35042 Rennes Cedex, France
R. Guérin
Affiliation:
Université de Rennes I, Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS-Université No. 6511, Avenue du Général Leclerc, 35042 Rennes Cedex, France
*
a)Author to whom correspondence should be addressed: Electronic mail: Patricia.Bé[email protected]
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Abstract

The two ternary phases W5As2.5P1.5 and Ni4Nb5P4 have been investigated by X-ray powder diffraction. Precise data for the two compounds were collected using CuKα1 radiation over the range 11°–140° 2θ. Unit cell refinements (space group I4/m) led to a=9.4729(3) Å, c=3.2414(2) Å (Dx=13.16 gcm−3) with M20=127, F30=91(0.0092,36) for W5As2.5P1.5 and a=9.9304(4) Å, c=3.5243(3) Å (Dx=7.87 gcm−3) with M20=179, F30=138(0.0068,32) for Ni4Nb5P4.

Keywords

W5As2.5P1.5 and Ni4Nb5P4:Ti5Te4-type ternary phosphidesX-ray powder diffractionindexings and refinements from powder diffraction datatetragonal unit cellshigh precision of powder diffraction data
Type
Research Article
Information
Powder Diffraction , Volume 14 , Issue 2 , June 1999 , pp. 126 - 129
Copyright
Copyright © Cambridge University Press 1999

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