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X-ray powder diffraction data for RuCI2(TRIPHOS)(DMSO) dichloro [bis(2-diphenylphosphinoethyl) phenylphosphine] [dimethylsulfoxide] ruthenium (II)

Published online by Cambridge University Press:  10 January 2013

Gerzon Delgado
Affiliation:
Departamento de Química, Facultad de Ciencias, Universidad de Los Andes Mérida, Mérida 5101, Venezuela
A. Valentina Rivera
Affiliation:
Departamento de Química, Facultad de Ciencias, Universidad de Los Andes Mérida, Mérida 5101, Venezuela
Trino Suárez
Affiliation:
Departamento de Química, Facultad de Ciencias, Universidad de Los Andes Mérida, Mérida 5101, Venezuela
Bernardo Fontal
Affiliation:
Departamento de Química, Facultad de Ciencias, Universidad de Los Andes Mérida, Mérida 5101, Venezuela

Abstract

X-ray powder diffraction data for Dichloro [bis(2-diphenylphosphinoethyl) phenylphosphine] [dimethylsulfoxide] Ruthenium (II) is reported. The powder pattern was obtained using CuKα radiation. The lattice parameters determinated by least-squares refinement for the monoclinic space group P21/c are: a = 21.073(3) Å, b = 11.970(2) Å, c = 16.889(3) Å, and β = 107.72(1)°, with M20 = 10.67 and F30 = 15.4 (0.0145, 134), and are in good agreement with those obtained from the single crystal structure determination. Observed and calculated X-ray powder diffraction data are given for the titled compound.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1995

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References

Delgado, G., Rivera, A. V., Suárez, T., and Fontal, B. (1994). “X-Ray Structure of Dichloro [bis(2-diphenylphosphinoethyl) phenylphosphine] [dimethyl-sulfoxide] Ruthenium (II),” submitted for publication to Inorg. Chim. Acta.Google Scholar
Garvey, R. (1992). PDFEAPC, “Powder Diffraction File Editorial Aids on a Personal Computer,” North Dakota State University.Google Scholar
McMurdie, H. F., Morris, M. C. Evans, E. H., Paretzkin, B., and Wong-Ng, W. (1986). “Methods of Producing Standard X-ray Diffraction Powder Patterns,” Powder Diffr. 1, 4043.CrossRefGoogle Scholar
Mighell, A. D., Hubbard, C. R., and Stalick, J. K. (1981). “NBS* AIDS80: A Fortran Program for Crystallographic Data Evaluation,” NBS Tech. Note 1141.CrossRefGoogle Scholar
Smith, D. K., and Smith, K. L. (1992). MICRO-POWD, “A Program for Calculating X-ray Powder Diffraction Patterns on a PC,” Livermore, CA 94551. Materials Data, Inc.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “FN: A criterion for rating powder diffraction patterns and evaluating the reability of powder pattern indexing,” J. Appl. Crystallogr. 12, 6065.CrossRefGoogle Scholar
Suárez, T., and Fontal, B. (1988). “Hydrogenation reactions with RuCl2(TRIPHOS),” J. Mol. Catal. 45, 335344.CrossRefGoogle Scholar
de Wolf, P. M. (1968). “A simplified criterium for the reability of a powder pattern indexing,” J. Appl. Crystallogr. 1, 108113.CrossRefGoogle Scholar