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Synthesis, characterization, and crystal structure of two zinc linear dicarboxylates

Published online by Cambridge University Press:  06 May 2016

Berenice Torruco Baca ,
Luis Felipe del Castillo ,
Paula Vera-Cruz ,
Rubén A. Toscano ,
Joelis Rodríguez-Hernández  and
Jorge Balmaseda Open the ORCID record for Jorge Balmaseda [Opens in a new window]
Berenice Torruco Baca
Affiliation:
Departamento de Polímeros, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México
Luis Felipe del Castillo
Affiliation:
Departamento de Polímeros, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México
Paula Vera-Cruz
Affiliation:
Departamento de Polímeros, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México
Rubén A. Toscano
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México
Joelis Rodríguez-Hernández
Affiliation:
Departamento de Polímeros, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México Departamento de Materiales Avanzados, Centro de Investigación en Química Aplicada, CIQA, Blvd. Enrique Reyna No. 140, C.P. 25294, Saltillo, Coahuila, México
Jorge Balmaseda*
Affiliation:
Departamento de Polímeros, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México D.F. C.P. 04510, México
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

Two different crystalline structures corresponding to a zinc adipate and a zinc succinate were determined combining: X-ray powder and single-crystal diffraction, infrared spectroscopy, thermal analysis, and true densities experiments. The zinc succinate crystal structure was determined by single-crystal X-ray diffraction. This compound crystallizes in the orthorhombic space-group Cccm with unit-cell parameters a = 4.792(1) Å, b = 21.204(6) Å, c = 6.691(2) Å, V = 679.8(3) Å3, and Z = 8. Zinc adipate crystal structure was refined from the laboratory X-ray powder diffraction data by the Rietveld method. It crystallizes in the monoclinic space group P2/c with unit-cell parameters, a = 16.2037(17)Å, b = 4.7810(2)Å, c = 9.2692(6)Å, β = 90.329(3)°, V = 718.07(9) Å3, and Z = 4. The thermal expansion of it was estimated in 5.40 × 10−5 K−1. This contribution is a step on the way to systematize the regularities in the coordination diversity between linear dicarboxylates and transition metal–inorganic buildings units of metal–organic frameworks.

Keywords

zinc dicarboxylateRietveldcrystal structurethermal expansion
Type
New Diffraction Data
Information
Powder Diffraction , Volume 31 , Issue 3 , September 2016 , pp. 229 - 232
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Copyright
Copyright © International Centre for Diffraction Data 2016 

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