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Synthesis and X-ray powder diffraction study of the elpasolite Cs2NaCeCl6

Published online by Cambridge University Press:  10 January 2013

R. Acevedo  and
V. Poblete
R. Acevedo
Affiliation:
Department of Basic Chemistry, Faculty of Physical and Mathematical Sciences, University of Chile, Tupper 2069, P.O. Box 2777, Santiago-Chile
V. Poblete
Affiliation:
Nuclear Energy Chilean Commission, Amunategui 95, P.O. Box 188-D, Santiago-Chile
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Abstract

The synthesis at 850 °C and the structural characterization of the elpasolite structure compound Cs2NaCeCl6 is reported space group Fm3m, a = 10.943(2) Å, V = 1310.4 (Å)3, Z = 4, M = 641.64, Dx = 3.252, and Dexp = 3.21. Powder diffraction data from a Rietveld structure refinement, are reported.

Type
Research Article
Information
Powder Diffraction , Volume 10 , Issue 4 , December 1995 , pp. 241 - 242
Copyright
Copyright © Cambridge University Press 1995

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References

1de Piante, A., Richardson, F. S., and Zameer-ul, Hasan, “Optical excitations and emission spectra of Cs2NaErCl6,” J. Chem. Phys. 82(3), 1102 (1985).CrossRefGoogle Scholar
2Gerlinger, H. and Schaack, G., “Crystal field states of the Ce+3 ion in CeF3. A demonstration of vibronic interactions in ionic rare earth compounds,” Phys. Rev. B 33(11), 7438 (1986).CrossRefGoogle Scholar
3Tanner, P. A., Kumar, V. V. Rabu Kant, Jayasankar, C. K., Reid, M. F., “Analysis of the spectral data and comparative energy levels parameterization for Ln3+ in cubic elpasolite crystals,” J. Allos. Comp. (in press).Google Scholar
4Downer, M. C., ‘Two photon spectroscopy of rare earth ions in condensed matter environment,” Ph.D. thesis, Harvard University, Cambridge (1983).Google Scholar
5Berry, M. T., “Electronic transitions in Lanthanide ions,” MSC thesis, University of Virginia (1987).Google Scholar