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Structural investigation of the nickel 3-methylglutarate from powder diffraction demonstrating adaptability of the inorganic skeleton of MIL-77

Published online by Cambridge University Press:  01 March 2012

Nathalie Guillou ,
Carine Livage ,
Julienne Chaigneau  and
Gérard Férey
Nathalie Guillou
Affiliation:
Institut Lavoisier, UMR CNRS C8637, Université de Versailles St-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, F-78035 Versailles, France
Carine Livage
Affiliation:
Institut Lavoisier, UMR CNRS C8637, Université de Versailles St-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, F-78035 Versailles, France
Julienne Chaigneau
Affiliation:
Institut Lavoisier, UMR CNRS C8637, Université de Versailles St-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, F-78035 Versailles, France
Gérard Férey
Affiliation:
Institut Lavoisier, UMR CNRS C8637, Université de Versailles St-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, F-78035 Versailles, France
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Abstract

Ni20[(C6H8O4)20(H2O)8]∙33H2O, a new nickel(II) 3-methylglutarate, was prepared hydrothermally (180 °C, 48 h, autogenous pressure) from a 1:1.5:2:180 mixture of nickel (II) sulphate hexahydrate, 3-methylglutaric acid, sodium hydroxide, and water. It crystallizes in the cubic system (space group P4332, Z=1) with a=16.8488(5) Å and V=4783.1(4) Å3. Its structure was solved from conventional X-ray powder diffraction data. It presents a three-dimensional network of edge-sharing nickel octahedra, lined by deprotonated organic anions. This remarkable oxide network with corrugated 20-membered rings is constructed from homochiral helices. The rings intersect each other to generate large crossing channels full of water along [111].

Keywords

hydrothermal synthesisnickel carboxylateshybrid metal oxidechiralitymicroporous materials
Type
Invited Articles
Information
Powder Diffraction , Volume 20 , Issue 4 , December 2005 , pp. 288 - 293
Copyright
Copyright © Cambridge University Press 2005

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