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A review of the crystallography and crystal chemistry of compounds in the BaO-CuOx system

Published online by Cambridge University Press:  10 January 2013

Winnie Wong-Ng  and
Lawrence P. Cook
Winnie Wong-Ng
Affiliation:
Ceramics Division, NIST, Gaithersburg, Maryland 20899
Lawrence P. Cook
Affiliation:
Ceramics Division, NIST, Gaithersburg, Maryland 20899
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Abstract

Literature data pertaining to the crystal chemistry, crystallography, and X-ray powder-diffraction properties of phases reported in the system BaO-CuOx are compiled. Reported phases include BaCuO2−2.12, BaCuO2.26−2.39, BaCuO2.5, Ba2CuO3+x, Ba2Cu3O5+x, BaCu2O2+x, Ba3Cu5O8, Ba3CuO4, BaCu3O4, Ba3Cu2O4+x, Ba5Cu3O6+x, and BaCu2O3. The existence of some of these phases, however, still has to be verified. Most of these compounds are nonstoichiometric in oxygen. Their oxygen content, and in some cases even their crystal structures, vary with oxygen partial pressure. There are also reported indications that the cations Ba and Cu are not stoichiometric in the cubic BaCuO2-type compounds.

Type
Research Article
Information
Powder Diffraction , Volume 9 , Issue 4 , December 1994 , pp. 280 - 289
Copyright
Copyright © Cambridge University Press 1994

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