Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-23T18:59:06.904Z Has data issue: false hasContentIssue false
  • English
  • Français

Powder X-ray diffraction study of disilver(1+) pentacyanonitrosylferrate(2−)

Published online by Cambridge University Press:  10 January 2013

V. Venegas ,
A. Gómez  and
E. Reguera
V. Venegas
Affiliation:
National Polytechnical Institute, IPN-ESFM, Lindavista 07738, Mexico D.F., Mexico
A. Gómez
Affiliation:
National Center for Scientific Research, P.O. Box 6990, Havana, Cuba
E. Reguera
Affiliation:
National Polytechnical Institute, IPN-ESFM, Lindavista 07738, Mexico D.F., Mexico
Get access Rights & Permissions [Opens in a new window]

Abstract

The crystal structure of disilver(1+) pentacyanonitrosylferrate(2−) was studied by X-ray powder diffraction. IR and Mössbauer spectroscopies, thermogravimetric analysis and density measurements were also carried out. This compound is monoclinic, and its lattice parameters are: a=10.986(3) Å, b=6.4080(10) Å, c=7.4545(19) Å, α=δ=90°, β=102.54°(2).

Type
Research Article
Information
Powder Diffraction , Volume 14 , Issue 3 , September 1999 , pp. 219 - 221
Copyright
Copyright © Cambridge University Press 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Amalvy, J. I., Varetti, E. L., Aymonino, P. J., Castellano, E. E., Piro, O. E., and Puente, G. (1986). “DTA-TGA, crystal and molecular structure determination and vibrational studies of potassium nitroprussidesesquiquarterhydrate, K 2[Fe(CN)5NO].1.25H 2O,” J. Crystallogr. Spectrosc. Res. 16, 537–555.Google Scholar
Bottomley, F., and White, P. (1979). “Redetermination on the structure of disodium pentacyanonitrosylferrate (sodium nitroprusside),” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B35, 2193–2195.Google Scholar
Castellano, E. E., Piro, O. E., Podjarny, A. D., and Rivero, B. E. (1978). “The crystal and molecular structure of strontium nitroprusside dihydrate,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B34, 2673–2676.Google Scholar
Garvey, R. (1989). “LSUCRI PC unit cell refinement with indexing for the personal computer,” Powder Diffr. 1, 114–116.Google Scholar
Gentil, L. A., Baran, E. J., and Aymonino, P. J. (1976). “On some divalent transition and post-transition metal nitroprussides,” Inorg. Chim. Acta 20, 251–262.Google Scholar
Mighell, A. D., Hubbard, C. R., and Stalik, J. K. (1981). “NBS*AIDS80: A FORTRAN program for crystallographic data evaluation,” US Natl. Bur. Stand. Tech. Note No. 1141 (NBS*AIDS83 is an expanded version of NBS*AIDS80).Google Scholar
Mullica, D. F., Sappenfield, E. L., Tippin, D. B., and Leschnitzer, D. H. (1989). “Synthesis, spectroscopic studies and crystal structure analysis of zinc nitrosylpentacyanoferrate trihydrate, Zn[Fe(CN)5NO].3H 2O,”Inorg. Chim. Acta 164, 99–103.Google Scholar
Mullica, D. F., Tippin, D. B., and Sappenfield, E. L. (1990). “The crystal structure of two nitroprussides: Mn[Fe(CN)5NO].3H 2O and Cd[Fe(CN)5NO].3H 2O,”Inorg. Chim. Acta 174, 129–135.Google Scholar
Reguera, E., Bertrán, J. F., Miranda, J., and Portilla, C. (1992). “Study of the dependence of Mössbauer parameters on the outer cation in nitroprussides,” J. Radioanal. Nucl. Chem. 165, 191–201.Google Scholar
Reguera, E., Dago, A., Gómez, A., and Bertrán, J. F. (1996). “Structural changes in insoluble metal nitroprussides on ageing,” Polyhedron 15, 3139–3145.Google Scholar
Rigotti, G., Puente, G., and Rivero, B. E. (1980). “Structure of thallium nitroprusside,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B36, 1475–1477.Google Scholar
Soria, D. B., Amalvy, I. J., Piro, O. E., Castellano, E. E., Aymonino, P. J. (1996). “Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb 2[Fe(CN)5NO],” J. Chem. Crystallogr. 26, 325–329.Google Scholar
Werner, P.-E., Eriksson, L., and Westdahl, M. (1985). “TREOR, a semi-exhaustive trial and error powder indexing program for all symmetries,” J. Appl. Crystallogr. 18, 367–370.Google Scholar