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The observation and crystal structure of titanium oxycarbonitride

Published online by Cambridge University Press:  10 January 2013

A. Chrysanthou
Affiliation:
Department of Materials Engineering and Materials Design, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom
N. Hassine
Affiliation:
Department of Materials Engineering and Materials Design, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom

Abstract

Titanium oxycarbonitride was observed to form during the carbothermic reduction of TiO2 in the presence of nitrogen. A powder diffraction pattern for this phase which is isomorphous with TiC, TIN, and TiO is presented. The crystal structure is further discussed in terms of the observed composition and lattice defects.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1994

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References

Ariya, S. M., and Bogdanova, N. I. (1960). “Electrical Conductivity of Certain Titanium and Vanadium Oxides,” Soviet Phys.-Solid State 1, 935939.Google Scholar
Brager, A. (1939). “An X-ray Examination of Titanium Nitride. Acta Physiocochim,” URSS. 11, 617632.Google Scholar
Ehrlich, P. (1939). “Phasenverhältnisse und Magnetisches Verhalten im System Titan/Sauerstoff,” Z. Elektochem. 45, 362370 (in German).Google Scholar
Ehrlich, P. (1949). “Uber die binären Systeme des Titans mit den elementen Stickstoff, Kohlenstoff, Bor und Beryllium,” Z. Anorg. Allg. Chem. 259, 16 (in German).Google Scholar
Kuylenstierra, U., and Magnéli, A. (1956). “New Modification of Titanium Oxide,” Acta Chem. Scand. 10, 11951196.Google Scholar
Rudy, E. (1969). “Compendium of Phase Diagram Data,” AFML-TR-65-2, Part V.Google Scholar
Toth, L. E. (1971). Transition Metal Carbides and Nitrides (Academic, New York).Google Scholar
Vasilev, Y. V., Khrycheva, D. D., and Ariya, S. M. (1963). “Magnetic Susceptibility of the Lower Oxides of Titanium,” Russ. J. Inorg. Chem. 8, 402404.Google Scholar