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New X-ray powder diffraction data for two triborates CsB3O5(CBO) and TlB3O5(TBO)

Published online by Cambridge University Press:  10 January 2013

M. Touboul ,
N. Pénin  and
L. Seguin
M. Touboul*
Affiliation:
Laboratoire de Réactivité et de Chimie des Solides, UPRES-A 6007, UPJV, 33 rue Saint-Leu, 80039 Amiens Cedex, France
N. Pénin
Affiliation:
Laboratoire de Réactivité et de Chimie des Solides, UPRES-A 6007, UPJV, 33 rue Saint-Leu, 80039 Amiens Cedex, France
L. Seguin
Affiliation:
Laboratoire de Réactivité et de Chimie des Solides, UPRES-A 6007, UPJV, 33 rue Saint-Leu, 80039 Amiens Cedex, France
*
a)Author to whom all correspondence should be addressed; electronic mail: [email protected]
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Abstract

Precise X-ray powder diffraction patterns of two isostructural triborates, CsB3O5(CBO) and TlB3O5(TBO), have been collected on a D5000 diffractometer with a primary monochromated beam (λ CuKα1=1.5406 Å). Refinement of indexed reflections in the space group P212121 led to: a=6.201(1) Å, b=8.514(2) Å, c=9.176(2) Å, Z=4, Dx=3.363 for CBO and a=5.2156(4) Å, b=8.2659(6) Å, c=10.2240(9) Å, Z=4, Dx=4.773 for TBO. The Smith–Snyder figures of merit are F30=53.0 (0.0101, 56) for CBO and F30=112.9 (0.0074, 36) for TBO. These values are much better than the previous ones published in Powder Diffraction File.

Keywords

cesium triboratethallium triborate
Type
Research Article
Information
Powder Diffraction , Volume 14 , Issue 3 , September 1999 , pp. 234 - 236
Copyright
Copyright © Cambridge University Press 1999

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