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New Copper (II) — Rare Earth (III) Compounds1 II. Crystal Chemistry of CuLn2Ge2O8, CuLn2Si4O12 and CuLn2Ge4O12

Published online by Cambridge University Press:  10 January 2013

U. Lambert  and
W. Eysel
U. Lambert
Affiliation:
Mineralogisch-Petrographisches Institut, Universitat Heidelberg, FRG
W. Eysel
Affiliation:
Mineralogisch-Petrographisches Institut, Universitat Heidelberg, FRG
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Abstract

Twenty seven new rare earth (Ln) compounds CuLn2 Ge2O8, CuLn2Ge4O12 and CuLn2Si4O12 have been synthesized. The powder diagrams were indexed and solid solutions of silicates and germanates were investigated. Structural variations with temperature, lanthanide contraction and Ge/Si substitution are described. Indications for second order phase transitions were found.

Keywords

Coppercrystal chemistrygermanateslanthanidesphase transitionsilicatessolid solution.
Type
Research Article
Information
Powder Diffraction , Volume 1 , Issue 3 , September 1986 , pp. 256 - 260
Copyright
Copyright © Cambridge University Press 1986

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References

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