Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-25T06:02:21.943Z Has data issue: false hasContentIssue false

High temperature X-ray diffraction study of phase decomposition in rapidly quenched Al–Ge–Si

Published online by Cambridge University Press:  10 January 2013

N. Mattern
Affiliation:
Institut für Festkörper und Werkstofforschung Dresden, D-01171 Dresden, Postfach 27 00 16, Germany
A. Teresiak
Affiliation:
Institut für Festkörper und Werkstofforschung Dresden, D-01171 Dresden, Postfach 27 00 16, Germany
T. Schubert
Affiliation:
Institut für Festkörper und Werkstofforschung Dresden, D-01171 Dresden, Postfach 27 00 16, Germany
W. Löser
Affiliation:
Institut für Festkörper und Werkstofforschung Dresden, D-01171 Dresden, Postfach 27 00 16, Germany
S. Doyle
Affiliation:
Institut für Festkörper und Werkstofforschung Dresden, D-01171 Dresden, Postfach 27 00 16, Germany

Abstract

The phase decomposition occurring during the heating of rapidly quenched Al–Ge–Si alloys has been investigated in situ by means of synchrotron radiation X-ray diffraction. The metastable Al–Ge phases formed in the as-quenched state transform during heating to Al and Ge. The addition of silicon decreases the transformation temperature. A Ge(Si) solid solution is indicated by a systematic change in the lattice constant of Ge as a result of the diffusion of Si from the Al matrix into the phase-separated Ge matrix.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Illgen, L., Mühlbach, H., Löser, W., Lindenkreuz, H. G., Alius, E., Rülicke, D., and Müller, M. (1991). “Preparation of ductile Al–Ge soldering foils by PFC technique,” Mater. Sci. Eng., A 133, 738741.CrossRefGoogle Scholar
Jacobson, D. M., and Humpston, G. (1991). “High power devices: Fabrication technology and developments,” Met. Mater. 7, 733739.Google Scholar
Klug, H. P., and Alexander, L. F. (1987). X-Ray Diffraction Procedures (Wiley, New York).Google Scholar
Köster, U. (1972). “Metastabile Phasen in extrem erstarrten Aluminium-Germanium Legierungen,” Z. Metallkde. 63, 472479.Google Scholar
Laridjani, M., Krishnanand, K. D., and Cahn, R. W. (1976). “An X-ray study by Guinier diffraction camera of Al–Ge alloys rapidly quenched from the melt,” J. Mater. Sci. 11, 16431652.CrossRefGoogle Scholar
Löchner, U., Pennartz, P. U., Miehe, G., and Fueß, H. (1993). “Synchrotron Powder Diffractometry at HASYLAB DORIS,” Z. Kristallogr. 204, 114.CrossRefGoogle Scholar
Mattern, N., Riedel, A., and Wassermann, A. (1993). “Quantitative phase analysis of Si 3N 4 ceramics using the powder diffraction standard data base,” Mater. Sci. Forum 133–136, 3944.CrossRefGoogle Scholar
Mittemeijer, E., van Mourik, J. P., and de Keijser, Th. H. (1981). “Unusal lattice parameters in two-phase systems after annealing,” Philos. Mag. A 43, 11571164.CrossRefGoogle Scholar
Ojha, S. N., Chattopadhyay, K., and Ramachandra Rao, P. (1985). “Phase transformations and metastable phase equilibria in Al–Ge alloy,” Mater. Sci. Eng. 73, 177185.CrossRefGoogle Scholar
Pearson, W. P. (1967). Handbook of Lattice Spacings and Structures of Metals (Pergamon, Oxford).Google Scholar
Rabinkin, A. (1989). “New applications for rapidly solidified brazing foils,” Weld. J. (Miami) 40, 3946.Google Scholar
Ramachandrarao, P., Scott, M. G., and Chadwick, G. A. (1972). “Constitution and microstructure of rapidly solidified aluminium–germanium alloys,” Philos. Mag. 25, 961982.CrossRefGoogle Scholar
Schubert, T., Löser, W., Teresiak, A., Mattern, N., and Bauer, H. D. (1995). “Preparation and phase transformations of melt-spun Al–Ge–Si brazing foils,” J. Mater. Sci. 32, 21812189.CrossRefGoogle Scholar
Suryanarayana, C., and Anantharaman, T. R. (1970). “Solidification of aluminium–germanium at high cooling rates,” J. Mater. Sci. 5, 9921004.CrossRefGoogle Scholar