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Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition

Published online by Cambridge University Press:  11 March 2015

D. Y. Leshok ,
N. N. Golovnev  and
S. D. Kirik
D. Y. Leshok
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
N. N. Golovnev
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
S. D. Kirik*
Affiliation:
Siberian Federal University, 660041, Krasnoyarsk, 79 Svobodny av., Russian Federation
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structure determined from X-ray powder diffraction data. The compound has an ionic structure. [CuCl4]2− and CystaH22+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO.

Keywords

copper dichloride (CuCl2)cystaminedisulfideX-ray powder crystal structure determinationthermal analysis
Type
Technical Articles
Information
Powder Diffraction , Volume 30 , Issue 2 , June 2015 , pp. 163 - 169
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Copyright
Copyright © International Centre for Diffraction Data 2015 

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