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Crystal-structure refinement of τ3-Cr4(Al, Si)11 by full-profile Rietveld analysis

Published online by Cambridge University Press:  01 March 2012

Franz Weitzer ,
Hailin Chen  and
Julius C. Schuster
Franz Weitzer
Affiliation:
Innovative Materials Group, Universität Wien, Währinger Str. 42, A-1090 Wien, Austria
Hailin Chen
Affiliation:
Innovative Materials Group, Universität Wien, Währinger Str. 42, A-1090 Wien, Austria
Julius C. Schuster
Affiliation:
Innovative Materials Group, Universität Wien, Währinger Str. 42, A-1090 Wien, Austria
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Abstract

Crystal structure of the triclinic ternary phase Cr4(Al, Si)11 was investigated by full-profile Rietveld analysis of powder diffraction data. Four hundred eighty-four reflections were refined to a final RBragg value of 5.00%. Cr4(Al, Si)11 is isostructural to Mn4Al11. Silicon atoms enter into the structure by partially replacing aluminium on the Al(1) and Al(2) sites.

Keywords

ternary intermetallic phaseCr4(Al, Si)11Rietveld refinement
Type
Technical Articles
Information
Powder Diffraction , Volume 22 , Issue 3 , September 2007 , pp. 253 - 255
Copyright
Copyright © Cambridge University Press 2007

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References

Bland, J. A. (1958). “Studies of aluminium-rich alloys with the transition metals manganese and tungsten. II. The crystal structure of δ(Mn-Al)-Mn4Al11, ” Acta Crystallogr.ACCRA9 11, 236–244.CrossRefGoogle Scholar
Chen, H. L., Weitzer, F., Schuster, J. C., Du, Y., and Xu, H. H. (2007). “The isothermal section of the Al-Cr-Si system at 800 °C and the crystal structure of τ 2-Cr3Al9Si, ” J. Alloys Compd.JALCEU 436, 313–318.CrossRefGoogle Scholar
Daams, J. L. C., Villars, P., and van Vucht, J. H. N. (1991). Atlas of Crystal Structure Types for Intermetallic Phases (ASM International, Materials Park, OH), Vol. 1, pp. 97–101.Google Scholar
Rietveld, H. M. (1969). “A profile refinement method for nuclear and magnetic structures, ” J. Appl. Crystallogr.JACGAR10.1107/S0021889869006558 2, 65–71.CrossRefGoogle Scholar
Robinson, K. (1953). “The structure of α(AlCrSi)-Cr4Si4Al13, ” Acta Crystallogr.ACCRA9 6, 854–859.CrossRefGoogle Scholar
Rodríguez-Carvajal, J. (1997). “Fullprof, Program for Rietveld refinement, ” Laboratories Léon Brillouin (CEA-CNRS), Saclay, France.Google Scholar
Weitzer, F., Chen, H. L., Du, Y., and Schuster, J. C. (2006). “The crystal structure of a new triclinic ternary phase: τ 3-Cr4(Al, Si)11, ” IntermetallicsIERME5 14, 224–226.CrossRefGoogle Scholar