Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-25T15:17:12.076Z Has data issue: false hasContentIssue false
  • English
  • Français

Chemical preparation and crystal data for two hydrated cyclotriphosphates SrMIP3O9⋅3H2O and their corresponding anhydrous SrMIP3O9 (MI=K+ and Tl+)

Published online by Cambridge University Press:  06 March 2012

Kacem Sbai ,
Khadija El Kababi  and
Saïd Belaaouad
Kacem Sbai
Affiliation:
Laboratoire de Recherches de Chimie-Physique Générale, Faculté des Sciences Ben M’Sik, BP 7955, Casablanca, Morocco
Khadija El Kababi
Affiliation:
Laboratoire de Recherches de Chimie-Physique Générale, Faculté des Sciences Ben M’Sik, BP 7955, Casablanca, Morocco
Saïd Belaaouad*
Affiliation:
Laboratoire de Recherches de Chimie-Physique Générale, Faculté des Sciences Ben M’Sik, BP 7955, Casablanca, Morocco
*
a)Electronic mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Methods of chemical preparation and crystal data are reported for four new condensed phosphates: two hydrated cyclotriphosphates with a general formula SrMIP3O9⋅3H2O (MI=K+,Tl+) and their corresponding anhydrous cyclotriphosphates SrMIP3O9 (MI=K+,Tl+). The two hydrated condensed phosphates, SrKP3O9⋅3H2O and SrTlP3O9⋅3H2O, belong to previously investigated structure types. SrKP3O9⋅3H2O and SrTlP3O9⋅3H2O are orthorhombic, Z=4, space group Pnma, with respectively the following unit-cell dimensions: a=9.082(2) Å, b=8.133(2) Å, c=15.009(2) Å, M(20)=49, F(25)=61(0.0052;79) and a=9.115(7) Å, b=8.139(7) Å, c=15.221(2) Å, M(20)=285, F(30)=522(0.000 411;140). SrKP3O9 and SrTlP3O9 are monoclinic, space group P21/m or P21, Z=4, with, respectively, the following unit-cell dimensions: a=14.957(1) Å, b=8.372(1) Å, c=7.909(1) Å, β=102.27(1)°, M(20)=81, F(24)=95(0.000 025;92) and a=14.544(2) Å, b=8.639(1) Å, c=7.727(1) Å, β=102.05(1)°, M(20)=66, F(30)=78(0.003 098;125).

Keywords

chemical preparationcrystal datacondensed phosphatescyclotriphosphates
Type
New Diffraction Data
Information
Powder Diffraction , Volume 18 , Issue 3 , September 2003 , pp. 233 - 235
Copyright
Copyright © Cambridge University Press 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Belaaouad, S., Sbai, K., and Jouini, A.(2000). “Chemical preparation, thermal behavior and crystal structure of a new cyclotriphosphate: SrNH4P3O9⋅3H2O,” Solid State Sci. 2, 655–661.Google Scholar
El Kababi, K. (2000). “Etudes structurale et thermique de trois nouveaux phosphates: SrRbP3O9⋅3H2O, SrKP3O9⋅3H2O et (NH3C6H4COOH)3H2P3O10⋅3H2O. Etude du comportment thermique des cyclotriphosphates isomorphes CuM4I(P3O9)2⋅4H2O (MI=NH4,K),” Thèse de Doctorat National, Université Hassan II-Mohammedia, Faculté des Sciences Ben M’Sik, Casablanca, Maroc.Google Scholar
El Kababi, K., Sbai, K., and Vilminot, S. (2000). “Synthesis, thermal behaviour and crystal structure of SrRbP3O9⋅3H2O,” C.R. Acad. Sci., Ser. IIc: Chim CASCFN 3, 693–701. a39, CASCFN Google Scholar
Jouini, A., and Durif, A.(1983). “Utilisation des résines dans la préparation des phosphates condensés,” C. R. Acad. Sci. Paris. 297 II, 573–580.Google Scholar
Louër, D., and Louër, M. (1972). “Automatic indexation of X-ray diffractograms by the program treor,” J. Appl. Crystallogr. JACGAR 5, 271–275. acr, JACGAR CrossRefGoogle Scholar
Louër, D., and Vargas, R. (1982). “Refinement program treor,” J. Appl. Crystallogr. JACGAR 15, 542–545. acr, JACGAR CrossRefGoogle Scholar