Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-23T11:04:16.305Z Has data issue: false hasContentIssue false
  • English
  • Français

X-ray powder diffraction studies of fibrillar zinc trimolybdates ZnMo3O10·nH2O (n=3.75,5,10)

Published online by Cambridge University Press:  10 January 2013

Wiesław Łasocha ,
Wiesław Surga  and
Alicja Rafalska-Łasocha
Wiesław Łasocha
Affiliation:
Faculty of Chemistry, Jagiellonian University, Ingardena 3, 3-060 Krakow, Poland
Wiesław Surga
Affiliation:
Institute of Chemistry, WSP Kielce, Che⁁cin˜ska 1, Poland
Alicja Rafalska-Łasocha
Affiliation:
Faculty of Chemistry, Jagiellonian University, Ingardena 3, 3-060 Krakow, Poland
Get access Rights & Permissions [Opens in a new window]

Abstract

The X-ray powder diffraction data of polycrystalline fibrillar zinc trimolybdates ZnMo3O10·3.75H2O, ZnMo3O10·5H2O, and ZnMo3O10·10H2O, are reported. An uncommon diffraction pattern was recorded in the case of the “wet fibers” of ZnMo3O10·10H2O, which could be indexed assuming a model of parallel fibers with translation disorder along the fiber axis. The powder diffraction patterns, lattice parameters, space groups, and other data describing these compounds are presented in this paper.© 1999 International Centre for Diffraction Data.

Type
Research Article
Information
Powder Diffraction , Volume 14 , Issue 4 , December 1999 , pp. 276 - 279
Copyright
Copyright © Cambridge University Press 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Appelman, D. E., Evans, H. T., and Handwerker, D. S. (1966). “Program X-ray, Geological Survey.”Google Scholar
Łasocha, W., and Lewinski, K. (1994). “PROSZKI—System of programs for powder diffraction data processing,” J. Appl. Crystallogr. 27, 437.CrossRefGoogle Scholar
Łasocha, W., Surga, W., Hodorowicz, S., and Schenk, H. (1997). “Crystal structure of fibrillar zinc trimolybdate ZnMo 3O 10·,”Cryst. Res. Technol. 32, 455.CrossRefGoogle Scholar
Meullemeestree, J., and Penigault, E. (1972). “Acidic zinc molybdates,” Bull. Soc. Chim. Fr. 3, 868.Google Scholar
Sonneveld, E., and Visser, J. W. (1975). “Automatic collection of powder data from photographs,” J. Appl. Crystallogr. 8, 1–7.CrossRefGoogle Scholar
Stroud, , and Millane, , (1995). “Diffraction by disordered polycristalline fibers,” Acta Crystallogr., Sect. A: Found. Crystallogr. 51, 71–790; “Analysis of disorder in biopolymer fibers,” Acta Crystallogr., Sect. A: Found. Crystallogr. 51, 790–800.CrossRefGoogle Scholar
Surga, W. (1995). “Studies on fibrillar forms of Zn (II) trimolybdate hydrates,” Pol. J. Chem. 69, 1738–1741.Google Scholar
Visser, J. W. (1969). “A fully automatic program for finding the unit cell from powder data,” J. Appl. Crystallogr. 2, 89–95.CrossRefGoogle Scholar
Werner, P., Eriksson, L., and Westdahl, M. (1985). “TREOR, a semi-exhaustive trial-and-error powder indexing program for all symetries,” J. Appl. Crystallogr. 18, 367–370.CrossRefGoogle Scholar