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X-ray powder diffraction data for a DACH Pt nitrate, cis-[bis(acetonitrile)]-[(1R,2R)-1,2-diaminocyclohexane-κN, κN′]platinum(II)nitrate (1:2) monohydrate

Published online by Cambridge University Press:  05 March 2012

R. Pažout ,
J. Maixner ,
P. Kačer  and
J. Housková
R. Pažout*
Affiliation:
Central Laboratories, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
J. Maixner
Affiliation:
Central Laboratories, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
P. Kačer
Affiliation:
Department of Organic Technology, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
J. Housková
Affiliation:
Department of Organic Technology, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

X-ray powder diffraction data, unit cell parameters, and space group for a new platinum-based anticancer complex cis-[bis(acetonitrile)]-[(1R,2R)-1,2-diaminocyclohexane-κN, κN′]platinum (II)nitrate (1:2) monohydrate, cis-[Pt(C2H3N)2(C6H14N2)](NO3)2·H2O, are presented [a=12.638(3) Å, b=12.153(2) Å, c=11.881(3) Å, β=95.145(4)°, space group P21, cell volume=1817.5 Å3, and Z=4]. All measured lines were indexed and are consistent with the P21 space group. No detectable impurities were observed.

Keywords

X-ray powder diffractioncrystal structureDACH Pt acetonitrile nitrate hydrate
Type
New Diffraction Data
Information
Powder Diffraction , Volume 26 , Issue 1 , March 2011 , pp. 66 - 69
Copyright
Copyright © Cambridge University Press 2011

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References

Abu-Surrah, A. S. and Kettunen, M. (2006). “Platinum group antitumor chemistry: Design and development of new anticancer drugs complementary to cisplatin,” Curr. Med. Chem.CMCHE7 13, 1337–1357.10.2174/092986706776872970CrossRefGoogle ScholarPubMed
Boultif, A. and Louër, D. (2004). “Powder pattern indexing with the dichotomy method,” J. Appl. Crystallogr.JACGAR 37, 724–731.10.1107/S0021889804014876CrossRefGoogle Scholar
Galanski, M., Arion, V. B., Jakupec, M. A., and Keppler, B. K. (2003). “Recent developments in the field of tumor-inhibiting metal complexes,” Curr. Pharm. Des.CPDEFP 9, 2078–2089.10.2174/1381612033454180Google ScholarPubMed
Ho, Y. P., Au-Yeung, S. C. F., and To, K. K. W. (2003). “Platinum-based anticancer agents: Innovative design strategies and biological perspectives,” Med. Res. Rev.ZZZZZZ 23, 633–655.10.1002/med.10038CrossRefGoogle ScholarPubMed
Pažout, R. and Maixner, J. (2010). “X-ray powder diffraction data for a DACH Pt iodide, cis-[diiodo(1R,2R)-1,2-diaminocyclohexane-κ N, κ N′] platinum(II),” Powder Diffr.PODIE2 25, 368–370.10.1154/1.3504593CrossRefGoogle Scholar
Smith, G. S. and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder indexing,” J. Appl. Crystallogr.JACGAR 12, 60–65.10.1107/S002188987901178XCrossRefGoogle Scholar