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Powder diffraction study of some mixed ligand complexes of Mn(II), Ni(II), Cu(II), Zn(II), and Cd(II)

Published online by Cambridge University Press:  05 March 2012

Ranjana Ghose  and
Rajesh Kumar
Ranjana Ghose*
Affiliation:
Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, Uttar Pradesh 221005, India
Rajesh Kumar
Affiliation:
Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, Uttar Pradesh 221005, India
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

The mixed ligand complexes of manganese(II), nickel(II), copper(II), zinc(II), and cadmium(II) involving aspartic acid and benzoic acid have been synthesized. The complexes were studied by various spectroscopic techniques such as infrared, electronic, X-ray diffraction, and magnetic measurements. The complexes were found to have octahedral geometry. The X-ray powder diffraction results show that the crystal systems of Mn(II)-Asp-Ben complex are hexagonal, and Ni(II)-Asp-Ben, Cu(II)-Asp-Ben, Zn(II)-Asp-Ben, and Cd(II)-Asp-Ben complexes are found to be triclinic. The value of unit-cell parameters and XRD data for the five mixed ligand complexes are reported.

Keywords

aspartic acidbenzoic acidmixed ligand complexes
Type
New Diffraction Data
Information
Powder Diffraction , Volume 26 , Issue 1 , March 2011 , pp. 82 - 87
Copyright
Copyright © Cambridge University Press 2011

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References

Azaroff, L. V. and Buerger, M. J. (1958). The Powder Method in X-Ray Crystallography (McGraw-Hill, New York), Vol. 98, pp. 106–122.Google Scholar
Battaglia, L. P., Corradi, A. B., Antolini, L., Marcotrigiano, G., Menabue, L., and Pellacani, G. C. (1982). “Coordination behavior of L-aspartic acid: Ternary nickel(II) complexes with imidazoles. Crystal and molecular structure of (L-aspartate) tris (imidazole) nickel(II),” J. Am. Chem. Soc.JACSAT 104, 2407–2411.10.1021/ja00373a013CrossRefGoogle Scholar
Battaglia, L. P., Corradi, A. B., Marcotrigiano, G., Menabue, L., and Pellacani, G. C. (1980). “Synthesis and spectroscopic and structural properties of bis(N-acetyl-DL-tryptophanato) copper(II) complex and its amine adducts. Effect of amines on the amino acid coordination. Crystal and molecular structure of diaquabis (N-acetyl-DL-tryptophanato) bis(pyridine)copper(II),” J. Am. Chem. Soc.JACSAT 102, 2663–2669.10.1021/ja00528a024CrossRefGoogle Scholar
Buhler, K., Pucher, B., Wenk, C., and Broz, J. (2009). “Influence of benzoic acid in high fibre diets on nutrient digestibility and VFA production in growing/finishing pigs,” Archives of Animal Nutrition 63, 127–136, and references therein.10.1080/17450390902723927CrossRefGoogle ScholarPubMed
Bukietyńska, K., Podsiadly, H., and Karweeka, Z. (2003). “Complexes of vanadium(III) with L-alanine and L-aspartic acid,” J. Inorg. Biochem.JIBIDJ 94, 317–325.10.1016/S0162-0134(03)00050-3CrossRefGoogle ScholarPubMed
Goodgame, M. and Johns, K. W. (1978). “Metal complexes of uridine and thymidine,” J. Chem. Soc. Dalton Trans.JCDTBI 1978, 1294–1297.10.1039/dt9780001294CrossRefGoogle Scholar
Ishizuka, H., Yamamoto, T., Arata, Y., and Fujiwara, S. (1973). “NMR study of amino acids and their derivatives. V. Structures and formation constants of zinc-L-aspartic acid complexes in aqueous solution,” Bull. Chem. Soc. Jpn.BCSJA8 46, 468–471.10.1246/bcsj.46.468CrossRefGoogle Scholar
Kartal, Z. and Senturk, S. (2005). “FT-IR spectroscopic study of M(benzoic acid)2Ni(CN)4 complexes (M=Ni, Cd, Co and Mn),” Z. Naturforsch., A: Phys. Sci.ZNASEI 60A, 285–288.CrossRefGoogle Scholar
Lewandowski, W. (1988). “Effect of heavy metals on the aromatic system of benzoic acid,” Arch. Environ. Contam. Toxicol.AECTCV 17, 131–138.10.1007/BF01055163CrossRefGoogle Scholar
Nakamoto, K. (1970). Infrared Spectra of Inorganic and Coordination Compounds, 2nd ed. (Wiley, New York).Google Scholar
Vandevijvere, S., Andjelovic, M., De Wil, M., Vinkx, C., Huybrechts, I., Van Loco, J., Van Oyen, H., and Goeyens, L. (2009). “Estimate of intake of benzoic acid in the Belgian adult population,” Food Addit. Contam.FACOEB 26, 958–968.10.1080/02652030902858939CrossRefGoogle ScholarPubMed
Wojciechowska, A., Lomozik, L., and Zielinski, S. (1987). “Potentiometric and spectral studies of complex formation of La(III), Pr(III) and Lu(III) with aspartic acid and asparagines,” Monatsch. Chem.MOCMB7 118, 1317–1324.10.1007/BF00810636CrossRefGoogle Scholar
Yasui, T. and Ama, T. (1975). “Metal complexes of amino acids. VIII. Carbon-13 nuclear magnetic resonances of cobalt(III) complexes containing L-aspartic and L-glutamic acids,” Bull. Chem. Soc. Jpn.BCSJA8 48, 3171–3174.10.1246/bcsj.48.3171CrossRefGoogle Scholar