Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-26T00:34:31.475Z Has data issue: false hasContentIssue false
  • English
  • Français

New Crystal Data for Seven Molybdates MIIUMo4O16 (MII = Mg,Mn,Cd,Ca,Hg,Sr,Pb)

Published online by Cambridge University Press:  10 January 2013

M.R. Lee ,
M. Quartern  and
S. Jaulmes
M.R. Lee
Affiliation:
Laboratoire de Cristallochemie du Solide, Tour 54, Universitié Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France.
M. Quartern
Affiliation:
Laboratoire de Cristallochemie du Solide, Tour 54, Universitié Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France.
S. Jaulmes
Affiliation:
Laboratoire de Physique, CNRS-UA 200, Faculté des Sciences Pharmaceutiques et Biologiques, 4 Avenue de l'Observatoire, 75270 Paris Cedex 06, France.
Get access Rights & Permissions [Opens in a new window]

Abstract

Seven isotopic molybdates MIIUMo4O16 have been synthesized by solid state reaction with MII = Mg, Mn, Cd, Ca, Hg, Sr, Pb. Single crystals of CaUMo4O16 were obtained. Previously reported as triclinic, this compound is monoclinic, space group P2/n. Unit-cell parameters for the seven compounds are:

MgUMo4O16: a = 11.393(2), b = 6.505(1), c = 7.918(2) Å, β = 89.81(3)°, V = 586.8(5) Å3, Z = 2, Dx = 5.12 Mg m−3;

MnUMo4O16: a = 11.413(2), b = 6.555(1), c = 8.023(1) Å, β = 89.86(2)°, V = 600.2(4)Å3, Z = 2, Dx = 5.18 Mg m−3;

CdUMo4O16: a = 11.427(2), b = 6.607(1), c = 8.144(2) Å3, β = 90.40(2)°, V = 614.8(5)Å3, Z = 2, Dx = 5.37 Mg m−3;

CaUMo4O16: a = 11.443(3), b = 6.653(2), c = 8.239(2)Å, β = 90.51(3)°, V = 627.2(6)Å3, Z = 2, Dm = 4.83(5), Dx = 4.88 Mg m−3;

HgUMo4O16: a = 11.439(3), b = 6.643(1), c = 8.257(2)Å, β = 90.53(3)°, V = 627.4(6)Å3, Z = 2, Dx = 5.73 Mg m−3;

SrUMo4O16: 11.465(3), b = 6.768(2), c = 8.492(2) Å, β = 90.86(3)°, V = 658.8(6)Å3, Z = 2, Dx = 4.88 Mg m−3;

PbUMo4O16: a = 11.470(4), b = 6.813(2), c = 8.557(2)Å, β = 90.88(4)°, V = 668.7(8)Å3, Dx = 5.41 Mg m−3;

Powder diffraction data for each phase are reported.

Type
Research Article
Information
Powder Diffraction , Volume 3 , Issue 2 , June 1988 , pp. 106 - 109
Copyright
Copyright © Cambridge University Press 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Lee, M. R. & Jaulmes, S. (1987). J. Solid State Chem. 67, 364–368.Google Scholar
Loopstra, B. (1964). Acta Crystallogr. 17, 651–654.Google Scholar
Marsh, R. E. (1987). J. Solid State Chem. (to be published).Google Scholar
Smith, G. S. & Snyder, R.L. (1969). J. Appl. Crystallogr. 12, 60–65.Google Scholar
Williams, D. E. (1964). LCR-2: A Fortran Lattice - Constant Refinement Program. U.S.A.E.C. Rep. US-1052.Google Scholar
Yvon, K., Jeitschko, W. & Parthé, E. (1977). J. Appl. Crystallogr. 10, 73–74.Google Scholar