Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-16T19:20:38.088Z Has data issue: false hasContentIssue false
  • English
  • Français

About the crystal structure of La1−xSrxCoO3−δ (0≤x≤0.6)

Published online by Cambridge University Press:  10 January 2013

Nicole M. L. N. P. Closset ,
René H. E. van Doorn ,
Henk Kruidhof  and
Jaap Boeijsma
Nicole M. L. N. P. Closset
Affiliation:
Laboratory of Inorganic Chemistry and Materials Science, Department of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, the Netherlands
René H. E. van Doorn*
Affiliation:
Laboratory of Inorganic Chemistry and Materials Science, Department of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, the Netherlands
Henk Kruidhof
Affiliation:
Laboratory of Inorganic Chemistry and Materials Science, Department of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, the Netherlands
Jaap Boeijsma
Affiliation:
Laboratory of Chemical Physics, Department of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, the Netherlands
*
a) Corresponding author; E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

The crystal structure of La1−xSrxCoO3−δ (0≤x≤0.6) has been studied, using powder X-Ray diffraction. The crystal structure shows a transition from rhombohedral distorted perovskite for LaCoO3−δ into cubic perovskite for La0.4Sr0.6CoO3−δ. The cubic unit cell parameter is ac=3.8342(1) Å for La0.4Sr0.6CoO3−δ, the space group probably being Pm3m. Using a hexagonal setting, the cell parameters for La0.5Sr0.5CoO3−δ, are a=5.4300(3) Å, c=13.2516(10) Å; a=5.4375(1) Å, c=13.2313(4) Å for La0.6Sr0.4CoO3−δ; a=5.4437(1) Å, c=13.2085(5) Å for La0.7Sr0.3CoO3−δ; a=5.4497(2) Å, c=13.1781(6) Å for La0.8Sr0.2CoO3−δ and a=5.4445(2) Å, c=13.0936(6) Å for LaCoO3−δ with the space group probably being R3c.

Type
Research Article
Information
Powder Diffraction , Volume 11 , Issue 1 , March 1996 , pp. 31 - 34
Copyright
Copyright © Cambridge University Press 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)