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Published online by Cambridge University Press: 27 March 2023
I describe two candidate representations of a mixture. The first, which I call the standard representation, is not a good representation of a mixture in spite of its widespread popularity. The second, which I call Gibbs’s representation, is less widely adopted but is, I argue, a much better representation. I show that once we have a precise mathematical structure that can be used to represent thermodynamic systems, and once an adequate perspective on representation is adopted, Gibbs’s representation trumps the standard representation.