Both Ni and alkaline earth metal oxide (MO: CaO, SrO, and BaO)-impregnated SDC powders were prepared as an SOFC anode material. The averaged Ni particle size on SDC was affected by the kind of alkaline earth metal oxide added. The addition of SrO and BaO to Ni/SDC anode enhanced power densities of both H2-SOFC and CH4-SOFC and the addition of CaO lowered them. The maximum power density increased with decreasing the averaged Ni particle size of Ni-MO/SDC anode.