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Zirconia Solubility in Boroaluminosilicate Glass

Published online by Cambridge University Press:  15 February 2011

S. V. Raman ,
R. Bopp ,
T. A. Batcheller  and
Q. Yan
S. V. Raman
Affiliation:
Idaho National Engineering Laboratory-Lockheed Idaho Technologies Company, Idaho Falls, Id.
R. Bopp
Affiliation:
Idaho National Engineering Laboratory-Lockheed Idaho Technologies Company, Idaho Falls, Id.
T. A. Batcheller
Affiliation:
Idaho National Engineering Laboratory-Lockheed Idaho Technologies Company, Idaho Falls, Id.
Q. Yan
Affiliation:
Chemistry Department, University of Houston, Houston, Tx.
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Abstract

In the Idaho Chemical Processing Plant (ICPP) waste streams, zirconia is often the waste load limiting species. It modifies the glass network, enhances durability, increases viscosity and induces crystallization. The limits of its dissolution in boroaluminosilicate glass, with magnesia and soda additions were experimentally determined. A ternary compositional surface is evolved to present the isothermal regimes of liquid, liquid+zircon, liquid+forsterite, and liquid phase sintered ceramic. The potential of partitioning the transuranics, transition elements and solutes in these regimes is discussed. The visible Raman spectroscopic results are presented to elucidate the dependence among glass composition, structure and chemical durability.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 412: Symposium V – Scientific Basis for Nuclear Waste Management XIX , 1995 , 113
Copyright
Copyright © Materials Research Society 1996

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References

1. Raman, S.V., Hot Isostatically Pressed Aluminosilicate Glass-Ceramic with Natural Crystalline Analogues for Immobilizing the Calcined High-Level Nuclear Waste at the Idaho Chemical Processing Plant, WINCO-1173, December 1993.Google Scholar
2. Raman, S.V., Formation of Natural Analogues in Nuclear Waste Forms: A Geochemical Approach, in Proceedings of the Sixth International High Level Radioactive Waste Management (IHLRWM) Conference, Las Vegas, NV. April 30th-May5th, pp. 594–596, 1995,Google Scholar
3. Jones, C., Mulloy, B. and Thomas, A.H., Methods in Molecular Biology, Humana Press, Inc., Totowa, NJ, vol.17, pp. 345–374. 1993.Google Scholar
4. Deer, W.A., Howie, R.A. and Zussman, J., An Introduction to the Rock-Forming Minerals, Longmans, p. 16, 1967.Google Scholar
5. Bloss, F.D., Crystallography and Crystal Chemistry, Holt, Rinehart and Winston, Inc., p. 216, 1971.Google Scholar
6. Cunnane, J.C., High-Level Waste Borosilicate Glass: A Compendium of Corrosion Characteristics, vol 1, DOE-EM-0177, p. 3, October, 1993.Google Scholar
7. Ellison, A.J.G. and Hess, P.C., Raman Study of Potassium Silicate Glasses Containing Rb÷, Sr2÷, Y3÷, and Zr4+: Implications for Cation Solution Mechanisms in Multicomponent Silicate Liquids, Geochim. et Cosmochim. Acta, vol.58, pp. 1877–1887, 1994.Google Scholar
8. McMillan, P., Structural Studies of Silicate Glasses and Melts-Applications and Limitations of Raman Spectroscopy, American Mineralogist, vol.69, pp. 622–644, 1984.Google Scholar