Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-29T07:50:22.640Z Has data issue: false hasContentIssue false
  • English
  • Français

X-Ray Spectroscopic Study of the PdxC60Chemical Bonding

Published online by Cambridge University Press:  15 February 2011

A.V. Okotrub ,
E.S. Fomin ,
V.N. Ivanova  and
L.N. Mazalov
A.V. Okotrub
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
E.S. Fomin
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
V.N. Ivanova
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
L.N. Mazalov
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
Get access

Abstract

The CKα -emission spectra of the PdxC60 compounds were obtained. To interpret the spectrum and study the Pd - C60 chemical bond structure, the SCF Xα-SW calculations of the clusters simulating the bonding between two fullerene molecules and a Pd bridge atom were carried out. On the base of the obtained data, a diagram of the electron interaction between the Pd atoms and fullerenes was constructed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 437: Symposium DD – Applications of Synchrotron Radiation to III , 1996 , 155
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Nagashima, H., Nakaoka, A., Saito, Y. et al., J. Chem. Soc., Chem. Commun. 377 (1992)Google Scholar
2. Chernov, V.A., Ivanova, V.N., Kozhevnikova, A.N. et al., Nuclear Instruments & Methods in physics research A359, 250–253 (1995)Google Scholar
3. Okotrub, A.V., Murakhtanov, V.V., Mazalov, L.N. et al. Dokl. Akad. Nauk 329 (6),.752–754 (1993).Google Scholar
4. Kawai, J., Maeda, K., Takami, M. et al., J.Chem.Phys. 98 (5), 3650–3655 (1993).Google Scholar
5. Okotrub, A.V., Murakhtanov, V.V., Shevtsov, Yu.V. et al., in Recent Advancas in Chemistry and Physics of Fullerenes and Related Materials: Volume2, edited by Ruoff, R.S., Kadish, K.M., 1995, pp. 678–682.Google Scholar
6. Okotrub, A.V., Yumatov, V.D., Mazalov, L.N., Zh. Strukt. Khim. 29 (2), 167–170 (1988).Google Scholar