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Wetting Angles and Surface Tension in the Crystallization of Thin Liquid Films

Published online by Cambridge University Press:  22 February 2011

Eli Yablonovitch  and
T. Gmitter
Eli Yablonovitch
Affiliation:
Exxon Research and Engineering Company Annandale, New Jersey 08801
T. Gmitter
Affiliation:
Exxon Research and Engineering Company Annandale, New Jersey 08801
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Abstract

The behaviour of thin liquid films is known to be dominated by surface tension forces. We show that the crystallization of thin liquid films requires that two wetting angle conditions be simultaneously satisfied: (i) relating to the liquid–vapour interface and (ii) relating to the crystal–liquid interface. The balance between capillary pressure and thermal gradient forces shows that the equilibrium freezing point of thin films is actually depressed below the bulk freezing point. The magnitude of the effect is 1°K in an 800 Å thick film. These observations suggest that small–scale thickness fluctuations may be responsible for the initiation of sub–grain boundaries in the growth of crystalline silicon films.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 23 , 1983 , 389
Copyright
Copyright © Materials Research Society 1984

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References

REFERENCES

1.Geis, M. W., Smith, H. I., Silversmith, D. J., Mountain, R. W. and Thompson, C. V., J. Electrochem. Soc. 130, 1178 (1983).Google Scholar
2.Adamson, A. W., Physical Chemistry of Surfaces, Third edition (John Wiley and Sons, New York, 1976).Google Scholar
3.Kim, K. M., Berkman, S., Temple, H. E. and Cullen, G. W.. J. Crys. Growth 50, 212 (1980).Google Scholar
4.Berkman, S. (private communication).Google Scholar
5.Whalen, T. J. and Anderson, A. T., J. Am. Ceram. Soc. 58, 396 (1975).Google Scholar
5a.Kuroda, E., Matsuda, M., and Maki, M., Phys. Stat. Sol. (a) 48, 105 (1978).Google Scholar
6.Brice, J. C., The Growth of Crystals from Liquids, North–Holland, Amsterdam, 1973) see especially p. 209.Google Scholar
7.Woodruff, D. P., The Solid–Liquid Interface (Cambridge Univ. Press, London, 1973) see especially p. 31.Google Scholar
8.Celler, G. K., private communication.Google Scholar
9.Handbook of Thermophysical Properties of Solid Materials, Vol. III – Ceramics ed. by Goldsmith, A., Waterman, T. E. and Hirschhorn, H. J. (Pergammon Press, NY, 1961) see especially p. 893.Google Scholar