Hostname: page-component-7bb8b95d7b-wpx69 Total loading time: 0 Render date: 2024-09-12T03:21:47.521Z Has data issue: false hasContentIssue false

VPI-5: A Novel Large Pore Molecular Sieve

Published online by Cambridge University Press:  28 February 2011

Mark E. Davis
Affiliation:
Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061
Carlos Saldarriaga
Affiliation:
Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061
Consuelo Montes
Affiliation:
Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061
Juan Garces
Affiliation:
The Dow Chemical Company, Midland, MI, 48640
Cyrus Crowder
Affiliation:
The Dow Chemical Company, Midland, MI, 48640
Get access

Abstract

This paper reports a novel family of aluminophosphate based molecular sieves denoted as VPI-5. These molecular sieves are the first to contain pores larger than 10 Å. The large pores of the VPI-5 sieves consist of long channels circumscribed by eighteen membered rings and are capable of adsorbing molecules excluded from other molecular sieves.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Breck, D. W., Zeolite Molecular Sieves, (Wiley, New York, 1974).Google Scholar
[2] Wilson, S. T., Lok, B. M., Messina, C. A., Cannan, T. R., and Flanigen, E. M., J. Am. Chem. Soc. 104 11461147 (1982).Google Scholar
[3] Flanigen, E. M., Lok, B. M., Patton, R. L., and Wilson, S. T. in New Developmnts in Zeolite Science and Technology, edited by Murakawi, X., lijima, A., and Ward, J. W. (Elsevier, Amsterdam, 1986), p. 103.Google Scholar
[4] Crowder, C., in preparation.Google Scholar
[5] Smith, J. V. and Dytrych, W. J., Nature 306, 607608 (1984).Google Scholar
[6] Meier, W. M. in New Developments in Zeolite Science and Technology, edited by Murakawi, X., lijima, A., and Ward, J. W. (Elsevier, Amsterdam, 1986), p. 13.Google Scholar
[7] Davis, M. E., Saldarriaga, C., Montes, C., Hathaway, P. E., Garces, J., Crowder, C., and Hasha, D., in preparation.Google Scholar