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UV Curable Polymers with Organically Modified Clay as the Nanoreinforcements

Published online by Cambridge University Press:  01 February 2011

Fawn M. Uhl ,
Brian R. Hinderliter ,
Siva Prashanth Davuluri ,
Stuart G. Croll ,
Shing-Chung Wong  and
Dean C. Webster
Fawn M. Uhl
Affiliation:
Center for Nanoscale Science and Engineering
Brian R. Hinderliter
Affiliation:
Department of Polymers and Coatings
Siva Prashanth Davuluri
Affiliation:
Department of Mechanical Engineering andApplied Mechanics North Dakota State University, P.O.Box 5376, Fargo, ND 58105
Stuart G. Croll
Affiliation:
Department of Polymers and Coatings
Shing-Chung Wong
Affiliation:
Department of Mechanical Engineering andApplied Mechanics North Dakota State University, P.O.Box 5376, Fargo, ND 58105
Dean C. Webster
Affiliation:
Department of Polymers and Coatings
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Abstract

UV curable polymers are prevalent in microelectronic applications. Several advantages are associated with UV curing such as rapid cure, solvent free systems, application versatility, low energy requirements, and low temperature operation. To be used in electronics the films must posses the following attributes: high glass transition, barrier properties, low shrinkage, flexibility, and enhanced mechanical properties. The area of polymer-clay nanocomposites have been widely investigated by researchers and improved mechanical, thermal, and barrier properties were reported. Most researchers have attempted nanocomposite formation by melt mixing or in situ polymerization. Little is understood on UV curable nanocomposites. This paper seeks to examine nanoclay-containing polymers using organomodified montmorillonites in UV curable systems and the effects of such clay inclusions on the properties of UV cured films. By x-ray diffraction it appeared that intercalated structures were formed. In the case of an epoxy acrylate formulation an increase in glass transition temperature was observed for formulations containing clay.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 788: Symposium L – Continuous Nanophase and Nanostructured Materials , 2003 , L11.45
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1. Alexandre, M., Dubois, P., Mater Sci. Eng., 2000, R28, 1.Google Scholar
2. Wang, W. J., Chin, W.-K., J. Polym. Sci. Part B: Polym. Physics, 2002, 40, 1690.Google Scholar
3. Tortora, M., Gorrasi, G., Vittoria, V., Galli, G., Ritrovati, S., Chiellini, E., Polym., 2002, 43, 6147.Google Scholar
4. Wu, J., Lerner, M. M., Chem. Mater., 1993, 5, 835.Google Scholar
5. Jackson, P., Paint and Resin Times, 2002, 1, 26.Google Scholar
6. Fouassier, J. P., ‘Photoinitiation, Photopolymerization, and Photocuring Fundamentals and Applications’, Hanser Publishers, 1995.Google Scholar
7. Decker, C., Zahouily, K., Keller, L., Benfarhi, S., Bendaikha, T., Baron, J., J. Mater. Sci., 2002, 37, 4831.Google Scholar
8. Uhl, F. M., Davuluri, S. P., Wong, S.-C., Webster, D. C., manuscript in preparation, 2003.Google Scholar
9. Uhl, F. M., Hinderliter, B. R., Davuluri, P., Croll, S. G., Wong, S. C., and Webster, D. C., Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 2003, 44, 247.Google Scholar
10. Uhl, F. M., Davuluri, S. P., Wong, S.-C., Webster, D. C., unpublished research, 2003.Google Scholar