Published online by Cambridge University Press: 26 February 2011
We report on the use of thermally-cracked tertiarybutylphosphine (TBP) and tertiarybutylarsine (TBA) with elemental Ga, In, and Al sources for the MOMBE growth of InP-based resonant tunneling diode (RTD) and resonant tunneling bipolar transistor (RTBT) structures. We have systematically examined the effects of growth conditions and heterostructure modifications on the InP/lnGaAs RTD including the use of pseudomorphic (InGa)P barriers and, in addition, explored for the first time, InP quantum well RTDs using both AlAs and InGaP barriers. Cross-sectional transmission electron microscopy has been used to correlate the structural quality with the electrical characteristics for both lattice-matched and pseudomorphic layers composed of InAs, AlAs, and InGaP. We also demonstrate the first use of mixed InP/lnGaAs and AlAs/lnGaAs heterojunctions in the RTBT. These transistors exhibit room temperature negative transconductance and a peak-to-valley current ratio of 35, the highest yet observed In the RTBT.