Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-27T01:43:43.680Z Has data issue: false hasContentIssue false
  • English
  • Français

The Use of Superlattice Reactants in The Synthesis of Ternary CU‐NB‐SE Compounds

Published online by Cambridge University Press:  21 February 2011

Marc D. Hornbostel ,
Masafumi Fukuto  and
David C. Johnson
Marc D. Hornbostel
Affiliation:
Department of Chemistry and Materials Science Institute, University of Oregon, Eugene, Oregon 97403
Masafumi Fukuto
Affiliation:
Department of Chemistry and Materials Science Institute, University of Oregon, Eugene, Oregon 97403
David C. Johnson
Affiliation:
Department of Chemistry and Materials Science Institute, University of Oregon, Eugene, Oregon 97403
Get access

Abstract

The low temperature interdiffusion of superlattice reactants of the binary systems niobium‐selenium and copper‐selenium and the ternary copper‐niobium‐selenium were explored to synthesize amorphous reaction intermediates. Controlled crystallization of this intermediate, which depends upon nucleation energetics rather than the thermodynamic stability of the final product, was used as we attempted to prepare ternary niobium cluster compounds. We present data demonstrating the ability to prepare amorphous ternary intermediates without the formation of crystalline binary compounds as reaction intermediates. Crystallization of the amorphous intermediate resulted in the formation of known ternary compounds directly, also without the formation of binary compounds.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 75
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Simon, A. Angewandte Chemie 1981, 20, 1–134.Google Scholar
2 Corbett, J. W. Ace. Chem. Res. 1981, 14, 239.Google Scholar
3 Chevrel, R.; Gougeon, P.; Potel, M.; Sergent, M. Journal of Solid State Chemistry 1985, 57, 25–33.Google Scholar
4 Fischer, , 6. Applied Physics 1978, 16, 1.Google Scholar
5 Yvon, K. Current Topics in Materials Science 1979, 3, 1–53.Google Scholar
6 Wertheim, G. K.; Rowe, J. E.; Buchanan, D. N. E.; Chaban, E. E.; Hebard, A. F.; Kortan, A. R.; Makhija, A. V.; Haddon, R. C. Science 1991, 252, 1419.Google Scholar
7 Haddon, R. C; Hebard, A. F.; Rosseinsky, M. J.; Murphy, D. W.; Duclos, S. J.; Lyons, K. B.; Miller, B.; Rosamilia, J. M.; Fleming, F. M.; Kortan, A. R.; Glarum, S. H.; Makhija, A. V.; Muller, A. J.; Eick, R. H.; Aahurak, S. M.; Tycko, R.; Dabbagh, G.; A., T. F. Nature 1991, 350,Google Scholar
8 Hebard, A. F.; Rosseinsky, M. J.; Haddon, R. C; Murphy, D. W.; Glarum, S. H.; Palstra, T. T. M.; Ramirez, A. P.; Kortan, A. R. Nature 1991, 350, 600.Google Scholar
9 Wells, A. F. Structural Inorganic Chemistry; 5 ed.; Clarendon Press: Oxford, 1984, pp 1–1382.Google Scholar
10 Tarascon, J. M., personal communication.Google Scholar
11 Novet, T.; Johnson, D. C. J. Am. Chem. Soc. 1991, 113, 3398–3403.Google Scholar
12 Novet, T.; Fister, L.; Grant, C. A.; Johnson, D. C. In Supramolecular Architecture: Synt/ietic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Vol. 499; pp 355–368.Google Scholar
13 Novet, T.; McConnell, J. M.; Johnson, D. C. Chemistry of Materials 1992, 4, 473–478.Google Scholar
14 Fister, L.; Johnson, D. C. In Structure and Properties of Interfaces in Materials ‐Materials Research Society Symposia; Clark, W. A. T., Dahmen, U. and Briant, C. L., Ed.; Materials Research Society: Boston, 1991; Vol. 238; pp 665–670.Google Scholar
15 Fister, L.; Johnson, D. C. J. Am. Chem. Soc. 1992, 114, 4639–4644.Google Scholar
16 Fister, Journal of the American Chemical Society 1993, 116, 629–633.Google Scholar
17 Novet, T.; McConnell, J. M.; Johnson, D. C. Materials Research Society 1992, 238, 581–586.Google Scholar
18 Fister, L. Ph.D. Thesis, University of Oregon 1993.Google Scholar
19 Schewe‐Miller, I. M.; F., Li; Columbia, M.; Schrader, G. L.; Franzen, H. F. Journal of Alloys and Compounds 1994, 204, L13–L15.Google Scholar