Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-29T07:40:35.749Z Has data issue: false hasContentIssue false
  • English
  • Français

The Use of Some Ion-Exchange Sorbing Tracer Cations in Insitu Experiments in High Saline Groundwaters

Published online by Cambridge University Press:  15 February 2011

J. Byegård ,
G. Skarnemark  and
M. Skålberg
J. Byegård
Affiliation:
Department of Nuclear Chemistry, Chalmers University of Technology, S-412 96 Göteborg, Sweden.
G. Skarnemark
Affiliation:
Department of Nuclear Chemistry, Chalmers University of Technology, S-412 96 Göteborg, Sweden.
M. Skålberg
Affiliation:
Department of Nuclear Chemistry, Chalmers University of Technology, S-412 96 Göteborg, Sweden.
Get access

Abstract

The possibility to use alkali metals and alkaline earth metals as slightly sorbing tracers in in-situ sorption experiments in high saline groundwaters has been investigated. The cation exchange characteristics of granite and some fracture minerals (chlorite and calcite) have been studied using the proposed cations as tracers. The results show low Kd’s for Na, Ca and Sr (∽0.1 ml/g), while the sorption is higher for the more electropositive cations (Rb, Cs and Ba). A higher contribution of irreversible sorption can also be observed for the latter group of cations. For calcite the sorption of all the tracers, except Ca, is lower compared to the corresponding sorption to granite and chlorite. Differences in selectivity coefficients and cation exchange capacity are obtained when using different size fractions of crushed granite. The difference is even more pronounced when comparing crushed granite to intact granite.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 353: Symposium – Scientific Basis for Nuclear Waste Management XVIII , 1994 , 1077
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Svenke, E. and Nilsson, L. B. (eds), Final Storage of Spent Nuclear Fuel - KBS-3. Swedish Nuclear Fuel and Waste Management Co., Stockholm 1983.Google Scholar
2. Albelin, H., Neretnieks, I., Tunbrant, S., and Moreno, L., Stripa Project Report Technical Report 85–03, Swedish Nuclear Fuel and Waste Management Co., Stockholm 1985.Google Scholar
3. Neretnieks, I., J. Geophys. Res., 85, 4379, (1980).Google Scholar
4. SKB RD & D Programme 1992, Swedish Nuclear Fuel and Waste Management Co., Stockholm 1992.Google Scholar
5. Wikberg, P., Gustafson, G., Rhén, I. and Stanfors, R., SKB Technical Report 91–22, Swedish Nuclear Fuel and Waste Management Co., Stockholm 1991.Google Scholar
6. Byegård, J., SKB Progress Report 25-93-14, Swedish Nuclear Fuel and Waste Management Co., Stockholm 1993.Google Scholar
7. Maloszewski, P. and Zuber, A., Institute of Nuclear Physics Rep. 1244 Ap, Cracow, (1984).Google Scholar
8. Huang, T.C. and Tsai, F.N., J. Inorg. Nucl. Chem., 32, 17, (1970).Google Scholar
9. Byegård, J., Skarnemark, G. and Skålberg, Mats, in Scientific Basis for Nuclear Waste Management XIV, edited by Abrajano, T. and Johnson, L.H., (Mat. Res. Soc. Proc., 212, Pittsburg, PA, 1990) pp 677–684.Google Scholar
10. Larsson, S. Å., Tullborg, E.L. and Lindblom, S., PRAV-report, 4–20, Swedish Nuclear Power Inspectorate, Stockholm, 1981.Google Scholar
11. Puigdomènech, I. and Nordstrom, K., SKB Technical Report 87–15, Swedish Nuclear Fuel and Waste Management Co., Stockholm 1987.Google Scholar
12. Byegård, J., Ph. D. thesis, (in prep.).Google Scholar
13. Cornell, R. M., J. Radioanal. Nucl. Chem, 171, 2, 483, (1993).Google Scholar
14. Sawhney, B. L., Soil Sci. Soc. Am. Proc., 33, 42, (1969).Google Scholar
15. Komarneni, S. and Roy, D.M., Clays Clay Miner., 28, 142, (1980).Google Scholar
16. Pingitore, N. E., in Geochemical Processes at Mineral Surfaces, edited by Davis, J.A. and Hayes, K.F. (ACS Symposium Series 323, Washington, DC, 1986), pp 574–586.Google Scholar