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The use of multinuclear solid state NMR for the characterization of siloxane-oxide hybrid nanocomposites

Published online by Cambridge University Press:  01 February 2011

Christel Gervais ,
Beatriz Julián ,
Eloisa Cordoncillo ,
Purificación Escribano ,
Mark E. Smith ,
Florence Babonneau  and
Clément Sanchez
Christel Gervais
Affiliation:
Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Beatriz Julián
Affiliation:
Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France Departamento de Química Inorgánica y Orgánica, Campus de Riu Sec, Universitat Jaume I, 12071, Castellón, Spain
Eloisa Cordoncillo
Affiliation:
Departamento de Química Inorgánica y Orgánica, Campus de Riu Sec, Universitat Jaume I, 12071, Castellón, Spain
Purificación Escribano
Affiliation:
Departamento de Química Inorgánica y Orgánica, Campus de Riu Sec, Universitat Jaume I, 12071, Castellón, Spain
Mark E. Smith
Affiliation:
Department of Physics, University of Warwick, Coventry, CV4 7AL, U.K
Florence Babonneau
Affiliation:
Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
Clément Sanchez
Affiliation:
Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
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Abstract

The objective of this paper is to review various solid state NMR techniques that have been, or can be used for the structural characterization of siloxane—oxide hybrid systems prepared by sol-gel process, and to discuss the type of information they provide, as well as their limitations. More precisely, this paper focuses on NMR techniques to probe and quantify the different types of oxo-bridges (M–O–M of oxide network, Si–O–Si of siloxane chains and Si–O–M siloxane–MxOy interface) in siloxane-oxide nanocomposites prepared through hydrolysis and condensation of organosilanes and M(OR)n alkoxides. In addition the influence of the functionality of the silicon alkoxides and the nature of the MxOy oxides on the extent of the Si-O-M interface will be examined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE6.2
Copyright
Copyright © Materials Research Society 2005

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