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UO2 Corrosion Study in Mineral Water: A Surface Analysis Approach

Published online by Cambridge University Press:  26 February 2011

P. Franco ,
P. Trocellier  and
F. Menes
P. Franco
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
P. Trocellier
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
F. Menes
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
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Abstract

Surface examination of sintered UO2 pellets, leached in groundwater at 90°C, have been conducted and the main results are described. They show the presence of a hydrated layer in which the uranium content decreases with leaching time. The oxidation state of uranium seems to remain (IV). The major components of the layer are magnesium and silicon. The growth of the surface layer in mineral water involves a decrease of uranium release in opposition to its continuing increase i n deionized water.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 127: Symposium BERLIN – Scientific Basis for Nuclear Waste Management XII , 1988 , 343
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Thomas, C.F. and Till, G., Nucl. Chem. Waste Manag. 5, 141 (1984).CrossRefGoogle Scholar
2. Kertes, A.S. and Guillaumont, R., Nucl. Chem. Waste Manag. 5, 215 (1985).CrossRefGoogle Scholar
3. Ollila, K., Nuclear Waste Commission of Finnish Power Companies, Report YJT 86–28, 1986 Google Scholar
4. Ministère français de la recherche et de l'industrie, Rapport du groupe de travail sur la gestion des combustibles irradiés, 1982.Google Scholar
5. Lahalle, M.P., Franco, P., Krupa, J.C., Dexpert, H., Trocellier, P., Hussonnois, M., Brillard, L. and Guillaumont, R., Poster present, for the 3rd Nat. Cong. of the French Chemical Society, Nice, Sept. 88.Google Scholar
6. Lahalle, M.P., Krupa, J.C., Guillaumont, R., Genet, M., Allen, G.C. and Holmes, N.R., Proc. for the 12th Int. Symp. on the Scientific Basis for Nuclear Waste Management, Berlin (FRG), Oct. 88, this volume.Google Scholar
7. Lahalle, M.P., Franco, P., Trocellier, P., Krupa, J.C., Genet, M., Allen, G.C. and Holmes, N.R., C.R. Acad. Sci. Paris 307, Série II, 1163 (1988).Google Scholar
8. Chu, W.K., Mayer, J.W. and Nicolet, M.A., Backscattering Spectrometry (Academic Press, New-York, 1978).CrossRefGoogle Scholar
9. Siegbahn, K. et al., ESCA. Atomic. Molecular and Solid State Structure Studied by Means of Electron Spectroscopy (Almqvist and Wiksells AB, Stockholm, 1967).Google Scholar
10. Pearson, R.L. and Wadsworth, M.E., Transactions of the Metallurgical Society of AIME, 294 (1958).Google Scholar
Wang, U.R. and Katayama, Y.B., Nucl. Chem. Waste Manag. 3, 83 (1982).CrossRefGoogle Scholar
12. Mauchien, P., Inorg. Chim. Acta 94, 139 (1983).CrossRefGoogle Scholar