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Universality of Dielectric Response as an Aid to Diagnostics

Published online by Cambridge University Press:  10 February 2011

Andrew K Jonscher*
Affiliation:
Royal Holloway, University of London Egham, Surrey, TW20 OEX
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Abstract

The advent of frequency response analysers and the formulation of the universality of dielectric responses have between them greatly enhanced the usefulness of dielectric measurements as a diagnostic tool. The available frequency range was extended to between eight and twelve decades, making it possible to determine spectra with some precision. In addition, we now have a much more complete understanding than was available previously of the significance of various spectral shapes. For charge carrier systems the universal approach is based on the fractional power law of frequency dependence of the real and imaginary components of the susceptibility , where the exponent falls in the range O < n < 1. Values of n close to unity correspond to low-loss behaviour, values close to zero to very lossy processes dominated by low-frequency dispersion (LFD). Examples will be presented of both extremes and an indication will be given of the theoretical significance of these results. A brief discussion will be given of the physical principles of low-loss dielectrics showing “flat” or frequency-independent χ and of the opposite limit of LFD. It will be shown how the presence of universality simplifies the analysis of data and their interpretation.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

[1] Jonscher, A K, Dielectric Relaxation in Solids, Chelsea Dielectrics Press, London, 1996 Google Scholar
[2] Jonscher, A K, Universal Relaxation Law, Chelsea Dielectrics Press, London, 1996 Google Scholar
[3] Havriliak, S Jr and Havriliak, J S, Dielectric and Mechanical Relaxation in Materials - Analysis, Interpretation and Application, Hanser Verlag 1996 Google Scholar
[4] Jonscher, A K, submitted to J Materials ScienceGoogle Scholar
[5] Isnin, A and Jonscher, A K, Ferroelectrics 210, 4765 (1998)Google Scholar
[6] Kuhn, A, León, C, Garcia-Alvarado, F, Santamaria, J, Moran, E and Alario-Franco, M A, IEEE Trans on Dielectrics and Insulation, to be publishedGoogle Scholar
[7] Lim, B S, Vaysleyb, A V and Nowick, A S, Applied Physics A 56, 814 (1993)Google Scholar
[8] Dyre, J C, J Non-Crystalline Solids, 135, 219226 (1991)Google Scholar
[9] Funke, K, Zeitschrift Fur Physikalische Chemie-International Journal Of Research In Physical Chemistry & Chemical Physics, 188, No. Ptl-2, Pp. 243257 (1995)Google Scholar