Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-20T04:03:02.865Z Has data issue: false hasContentIssue false
  • English
  • Français

Ultrasound-induced Functionalization and Solubilization of Carbon Nanotubes for Potential Nanotextiles Applications

Published online by Cambridge University Press:  01 February 2011

Wei Chen  and
Xiaoming Tao
Wei Chen
Affiliation:
[email protected], The Hong Kong Polytechnic University, Institute of Textiles and Clothing, Hung Hom, Kowloon, Hong Kong, Hong Kong, Hong Kong, Hong Kong, China, People's Republic of, 00852-34003174
Xiaoming Tao
Affiliation:
[email protected], The Hong Kong Polytechnic University, Hong Kong, China, Hong Kong, China, People's Republic of
Get access

Abstract

A simple sonochemical method has been employed for the surface functionalization of carbon nanotubes. Pristine single-walled carbon nanotubes (SWNTs) were irradiated by ultrasound in methyl methacrylate monomer. Polymer grafted carbon nanotubes were easily prepared by in situ sonochemically initiated radical polymerization of methyl methacrylate. FT-IR, TGA, SEM and TEM were used to characterize the polymethyl methacrylate (PMMA) grafted SWNTs. The surface-modified SWNTs afforded are then dispersible in good solvents for PMMA, such as dichloromethane and chloroform. The ‘green’ value involved in this simplifying processing contains low hazard, clean operation, reduced chemical consumption and short time, which undoubtedly generate profound impact on the development of carbon nanotube based nanochemistry and large scale nanotextiles application.

Keywords

nanostructurepolymerchemical reaction
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 920: Symposium S – Smart Nanotextiles , 2006 , 0920-S02-02
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Iijima, S., Nature 354, 56 (1991).Google Scholar
2. Boughman, R. H., Zakhidov, A. A., Heer, W. A. De, Science 297, 787 (2002).Google Scholar
3. Chen, J., Hamon, M. A., Hu, H., Chen, Y., Rao, A. M., Eklund, P. C., Haddon, R. C., Science 282, 95 (1998).Google Scholar
4. Liu, J., Rinzler, A. G., Dai, H., Hafner, J. H., Bradley, R. K., Boul, P. J., Lu, A., Terry, I., Konstantin, S., Huffman, C. B., Rodriguez-Macias, F., Shon, Y.S., Lee, T. R., Colbert, D. T., Smalley, R. E., Science 280, 1253 (1998).Google Scholar
5. Qin, S., Qin, D., Ford, W. T., Resasco, D. E., Herrera, J. E., J. Am. Chem. Soc. 126, 170 (2004).Google Scholar
6. Sun, Y. P., Fu, K., Lin, Y., Huang, W., Acc. Chem. Res. 35, 1096 (2002).Google Scholar
7. Mason, J., Lorimer, J. P., Sonochemistry: Theory, Applications and Users of Ultrasound in Chemistry; Ellis Horwood: Chichester. UK, 1988.Google Scholar
8. Suslick, K. S., Science 3, 1439 (1990).Google Scholar
9. Suslick, K. S., Ultrasound-Its Chemical, Physical, and biological Effects, VCH publishers, Inc., New York, 1988.Google Scholar
10. Ni, B., Sinnott, S. B., Phys. Rev. B 61, R16343 (2000).Google Scholar
11. Chen, W., Tao, X. M., Liu, Y. Y., Composite Science and Technology, 2006, (in press).Google Scholar
12. Chen, W., Tao, X. M., Macromolecular Rapid Communications 26, 1763 (2005).Google Scholar
13. Chen, W., Tao, X.M., Xue, P., Cheng, X.Y., Applied Surface Science 252, 1404 (2005).Google Scholar
14. Martel, R., Shea, H. R., Avouris, P., J. Phys. Chem. 103, 7551 (1999).Google Scholar