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Ultrananocrystalline Diamond-Biomolecular Composites: Towards BioMEMS

Published online by Cambridge University Press:  15 February 2011

N. M. Haralampus Grynaviski ,
O. Auciello ,
J. A. Carlisle ,
J. E. Gerbi ,
D. M. Gruen ,
J. F. Moore ,
A. Zinovev  and
M. A. Firestone
N. M. Haralampus Grynaviski
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
O. Auciello
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439. Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
J. A. Carlisle
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439. Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
J. E. Gerbi
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
D. M. Gruen
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439. Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
J. F. Moore
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
A. Zinovev
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
M. A. Firestone
Affiliation:
Materials Science Division and the Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439. Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439.
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Abstract

The surface functionalization of ultrananocrystalline (UNCD) thin films has been investigated to develop biocomposite materials for use as BioMicroElectroMechanical Systems (BioMEMS). Specifically, hydrophobic, hydrogen-terminated UNCD films have been synthesized using a microwave plasma chemical vapor deposition technique then surface functionalized using a two-step modification procedure. This procedure produces a mixed submonolayer comprised of chloro- and hydroxyl- terminated alkyl chains chemisorbed to the UNCD surface. This surface modification procedure serves to provide functional groups that will allow for the subsequent attachment of a wide variety of biological macromolecules (e.g., proteins, biomembranes) and the ability to tune the hydrophilic nature of the diamond. The resultant materials have been characterized using surface-sensitive spectroscopies (NEXAFS and XPS).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 773: Symposium N – Biomicroelectromechanical Systems (BioMEMS) , 2003 , N11.4
Copyright
Copyright © Materials Research Society 2003

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