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Two- and Three-Dimensional Ultrananocrystalline Diamond (UNCD) Structures for a High Resolution Diamond-Based MEMS Technology

Published online by Cambridge University Press:  10 February 2011

O. Auciello
Affiliation:
Argonne National Laboratory, Materials Science Division, Argonne, IL 60439
A.R. Krauss
Affiliation:
Argonne National Laboratory, Materials Science and Chemistry Divisions, Argonne, IL 60439
D.M. Gruen
Affiliation:
Argonne National Laboratory, Materials Science and Chemistry Divisions, Argonne, IL 60439
E.M. Meyer
Affiliation:
Institute for Microsensors, Actuators, and Systems (IMSAS), University of Bremen, Bremen
H.G. Busmann
Affiliation:
Fraunhofer Institute for Applied Materials Science, (IFAM), Bremen
J. Tucek
Affiliation:
Argonne National Laboratory, Materials Science and Chemistry Divisions, Argonne, IL 60439
A. Sumant
Affiliation:
Argonne National Laboratory, Materials Science and Chemistry Divisions, Argonne, IL 60439
A. Jayatissa
Affiliation:
Argonne National Laboratory, Materials Science and Chemistry Divisions, Argonne, IL 60439
N. Moldovan
Affiliation:
Experimental Facilities Division, Argonne National Laboratory, Argonne, Illinois 60439
D. C. Mancini
Affiliation:
Experimental Facilities Division, Argonne National Laboratory, Argonne, Illinois 60439
M. N. Gardos
Affiliation:
M. N. Gardos, Raytheon Electronic Systems, 2000 El Segundo, CA 90245
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Abstract

Silicon is currently the most commonly used material for the fabrication of microelectromechanical systems (MEMS). However, silicon-based MEMS will not be suitable for long-endurance devices involving components rotating at high speed, where friction and wear need to be minimized, components such as 2-D cantilevers that may be subjected to very large flexural displacements, where stiction is a problem, or components that will be exposed to corrosive environments. The mechanical, thermal, chemical, and tribological properties of diamond make it an ideal material for the fabrication of long-endurance MEMS components. Cost-effective fabrication of these components could in principle be achieved by coating Si with diamond films and using conventional lithographic patterning methods in conjunction with e. g. sacrificial Ti or SiO2 layers. However, diamond coatings grown by conventional chemical vapor deposition (CVD) methods exhibit a coarse-grained structure that prevents high-resolution patterning, or a fine-grained microstructure with a significant amount of intergranular non-diamond carbon. We demonstrate here the fabrication of 2-D and 3-D phase-pure ultrananocrystalline diamond (UNCD) MEMS components by coating Si with UNCD films, coupled with lithographic patterning methods involving sacrificial release layers. UNCD films are grown by microwave plasma CVD using C60-Ar or CH4-Ar gas mixtures, which result in films that have 3-5 nm grain size, are 10-20 times smoother than conventionally grown diamond films, are extremely resistant to corrosive environments, and are predicted to have a brittle fracture strength similar to that of single crystal diamond.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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