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Published online by Cambridge University Press: 28 February 2011
The mixed conducting LixMO2O4 system was shown to exhibit a high energy density (530Wh/kg) and average voltage (3.1V), suggesting that it would be a good candidate for a cathode in a Li-anode secondary battery. The transport properties of these oxide materials were then investigated by solid state 7Li NMR, dc and ac electrical measurements. The following phases are emphasized in this study: Li1.3MO204, Li2MO204, and the hydrated phase Li0.5 (H20) 1.3MO2O4.