Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-27T01:44:22.218Z Has data issue: false hasContentIssue false
  • English
  • Français

Trace Water Detection in Phosphine By Cavity Ring-down Spectroscopy

Published online by Cambridge University Press:  11 February 2011

Susan Y. Lehman ,
Kris A. Bertness  and
Joseph T. Hodges
Susan Y. Lehman
Affiliation:
National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305
Kris A. Bertness
Affiliation:
National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305
Joseph T. Hodges
Affiliation:
National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, MD 20899
Get access

Abstract

We are using cavity ring-down spectroscopy (CRDS) to measure concentrations of water in nitrogen and, for the first time to our knowledge, in phosphine. Water vapor concentrations have been measured in purified and unpurified phosphine, indicating a water mole fraction of (22.0 ± 1.0) x 10-6 in unpurified phosphine. After purification with an in-line, chemically-reactive purifier, the mole fraction of water in phosphine was less than 0.1 × 10-6. Mole fractions as high as (730 ± 60) × 10-6 have been measured in unpurified phosphine, suggesting that the H2O vapor concentration increases substantially with time as the gas is stored in a cylinder. The materials properties of AlInP grown by molecular beam epitaxy (MBE) with CRDS-characterized PH3 were found to be relatively insensitive to water contamination at the 22 mol/mol level.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 744: Symposium M – Progress in Semiconductors II–Electronic and Optoelectronic Applications , 2002 , M7.8
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. O'Keefe, A. and Deacon, D. A. G., Rev. Sci. Instrum. 59, 2544 (1988).Google Scholar
2. van Zee, R. D., Hodges, J. T., and Looney, J. P., Appl. Optics 38, 3951 (1999).Google Scholar
3. Schermaul, R., Learner, R. C. M., Newnham, D. A. et al., J. Mol. Spectrosc. 208, 32 (2001).Google Scholar
4. Schermaul, R., Learner, R. C. M., Newnham, D. A. et al., J. Mol. Spectrosc. 208, 43 (2001).Google Scholar
5. Lehman, S. Y., Bertness, K. A., and Hodges, J. T., J. Cryst. Growth (in press).Google Scholar
6. Funke, H. H., Raynor, M. W., Yücelen, B. et al., J. Electron. Mater. 30, 1438 (2001).Google Scholar
7. Bertness, K. A., Kurtz, S. R., Asher, S. E. et al., J. Cryst. Growth 196, 13 (1999).Google Scholar