Hostname: page-component-cd9895bd7-lnqnp Total loading time: 0 Render date: 2024-12-27T01:46:26.348Z Has data issue: false hasContentIssue false
  • English
  • Français

Thin-Film Synthesis and Cyclic Oxidation Behavior of B2-RuAl

Published online by Cambridge University Press:  01 February 2011

Karsten Woll ,
Rama Chinnam  and
Frank Mücklich
Karsten Woll
Affiliation:
[email protected], Saarland University, Materials Science and Engineering, Functional Materials, Saarbrücken, Germany
Rama Chinnam
Affiliation:
[email protected], Saarland University, Materials Science and Engineering, Functional Materials, Saarbrücken, Germany
Frank Mücklich
Affiliation:
[email protected], Saarland University, Materials Science and Engineering, Functional Materials, Saarbrücken, Germany
Get access

Abstract

B2-RuAl as a potential intermetallic for thin-film applications at high temperatures is studied with respect to thin-film synthesis and cyclic oxidation behaviour. Using the multilayer approach, single phase RuAl thin films were fabricated. The phase sequence from the elements Ru and Al goes through RuAl6 to the final product RuAl. To understand the reaction mechanism calorimetric as well as kinetic experiments were performed. The cyclic oxidation behavior is characterized at 1200 °C up to 47 h. The morphology of the grown alumina shows no cracks or regions of spallation which indicates the good cyclic oxidation behavior. Compressive stresses in the oxidation scale of about 1.2 GPa at maximum were determined.

Keywords

thin filmnucleation & growthoxidation
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1128: Symposium U – Advanced Intermetallic-Based Alloys for Extreme Environment and Energy Applications , 2008 , 1128-U06-10
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Levi, C.G., Curr. Opin. Solid State Mater. Sci. 8, 77 (2004)Google Scholar
[2] Shi, J., Darzens, S., Karlsson, A.M., Mater. Sci. Eng., A 392, 301 (2005)Google Scholar
[3] Kang, C.Y., Chen, Y.I., Lin, C.H., Duh, J.G., Appl. Surf. Sci. 253, 6191 (2007)Google Scholar
[4] Zhong, D., Mateeva, E., Dahan, I., Moore, J.J., Mustoe, G.G.W., Ohno, T., Disam, J., Thiel, S., Surf. Coat. Technol. 133–134, 8 (2000)Google Scholar
[5] Sauthoff, G., Intermetallics, VCH Verlagsgesellschaft, Weinheim, 1995 Google Scholar
[6] Soldera, F., Ilic, N., Brännström, S., Barrientos, I., Gobran, H.A., Mücklich, F., Oxid. Met. 59, 529 (2003)Google Scholar
[7] Tryon, B., Pollock, T.M., Gigliotti, M.F.X., Hemker, K., Scr. Mater. 50, 845 (2004)Google Scholar
[8] Mücklich, F., Ilic, N., Intermetallics 13, 5 (2005)Google Scholar
[9] Mücklich, F., Ilic, N., Woll, K., Intermetallics 16, 593 (2008)Google Scholar
[10] Wolff, I.M., JOM 1, 34 (1997)Google Scholar
[11] Bellina, P., Catanoiu, A., Morales, F.M., Rühle, M., J. Mater. Res. 21, 276 (2006)Google Scholar
[12] Cao, F., Nandy, T.K., Stobbe, D., Pollock, T.M., Intermetallics 15, 34 (2007)Google Scholar
[13] Zariff, A., Chaudhury, C., Suryanarayana, C., J. Mater. Sci. 17, 3158 (1982)Google Scholar
[14] Kissinger, H. E., J. Res. Natl. Bur. Stand. 57, 217 (1956)Google Scholar
[15] Ladwig, P.F., Chang, Y.A., Linville, E.S., Morrone, A., Gao, J., Pant, B.B., Schlutz, A.E., Mao, S., J. Appl. Phys. 94, 979 (2003)Google Scholar
[16] Criado, J. M. and Ortega, A., Acta Metall. 35, 171 (1987)Google Scholar
[17] Schütze, M., Protective Oxide Scales and Their Breakdown, John Wiley & Sons (1997)Google Scholar
[18] Tolpygo, V.K., Clarke, D.R., Oxid. Met. 49, 187 (1998)Google Scholar