Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-25T15:47:59.459Z Has data issue: false hasContentIssue false

The Thermodynamics of the Glass Transition

Published online by Cambridge University Press:  15 February 2011

Mats Hillert*
Affiliation:
Div. of Physical Metallurgy, Royal Inst. Techn. S-l00 44 Stockholm, Sweden
Get access

Abstract

The kinetic theory of the glass transition is examined. Some modifications are suggested in order to overcome some shortcomings. As a result, a thermodynamic description of the glass transition is obtained. It is demonstrated that the glass transition represents the beginning of a very gradual process of melting in the amorphous state.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Polk, D.E. and Giessen, B.C., Metallic Glasses, A.S.M., Metals Park 1978, pp. 135.Google Scholar
2.Cohen, M.H. and Turnbull, D., J. Chem. Phys. 31, 1164 (1959).10.1063/1.1730566Google Scholar
3.Turnbull, D. and Cohen, M.H., J. Chem. Phys. 34, 120 (1961).10.1063/1.1731549Google Scholar
4.Spaepen, F. and Turnbull, D., Metallic Glasses, A.S.M., Metals Park 1978. pp. 114127.Google Scholar
5.Frenkel, J., Kinetic Theory of Liquids, Oxford Univ. Press., Oxford 1946.Google Scholar
6.Ramachandrarao, P., Cantor, B. and Cahn, R.W., J. Mater. Sci. 12, 2488 (1977).10.1007/BF00553936Google Scholar
7.Doolittle, A.K., J. Appl. Phys. 22, 1471 (1951).10.1063/1.1699894Google Scholar
8.Williams, M.F., Landel, R.F. and Ferry, J.D., J. Amer. Chem. Soc. 77, 3301 (1955).Google Scholar
9.Saito, S., Treatise on Solid State Chemistry, Vol. 5, 1975 pp 513554.Google Scholar
10.Taub, A.I. and Spaepen, F., Acta Met. 28, 1781 (1980).10.1016/0001-6160(80)90031-0Google Scholar
11.Hildebrand, J.H. and Scott, R.L., Regular Solutions, Prentice-Hall, New Jersey, 1962.Google Scholar
12.Chen, H.S. and Turnbull, D., J. Chem. Phys. 48, 2260 (1968).Google Scholar
13.Hillert, M. and Staffansson, L-I, Acta Chem. Scand. 24, 3618 (1970).10.3891/acta.chem.scand.24-3618Google Scholar
14.Thomson, C.V. and Spaepen, F., Acta Met., 27, 1855 (1979).10.1016/0001-6160(79)90076-2Google Scholar
15.Gibbs, J.H. and DiMarzio, E.A., J. Chem. Phys. 28, 373 (1958).10.1063/1.1744141Google Scholar
16.Cohen, M.H. and Grest, G.S., Phys. Rev. B20, 1077 (1979).10.1103/PhysRevB.20.1077Google Scholar
17.Borelius, G., Sol. State Phys. 15, 1 (1963).10.1016/S0081-1947(08)60591-3Google Scholar