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Thermodynamic Coupling of Heat and Matter Flows in Near-Field Regions of Nuclear Waste Repositories

Published online by Cambridge University Press:  25 February 2011

C. L. Carnahan
C. L. Carnahan*
Affiliation:
Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
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Abstract

In near-field regions of nuclear waste repositories, thermodynamically coupled flows of heat and matter can occur in addition to the independent flows in the presence of gradients of temperature, hydraulic potential, and composition. The following coupled effects can occur: thermal osmosis, thermal diffusion, chemical osmosis, thermal filtration, diffusion thermal effect, ultrafiltration, and coupled diffusion. Flows of heat and matter associated with these effects can modify the flows predictable from the direct effects, which are expressed by Fourier's law, Darcy's law, and Fick's law. The coupled effects can be treated quantitatively together with the direct effects by the methods of the thermodynamics of irreversible processes. The extent of departure of fully coupled flows from predictions based only on consideration of direct effects depends on the strengths of the gradients driving flows, and may be significant at early times in backfills and in near-field geologic environments of repositories. Approximate calculations using data from the literature and reasonable assumptions of repository conditions indicate that thermal-osmotic and chemical-osmotic flows of water in semipermeable backfills may exceed Darcian flows by two to three orders of magnitude, while flows of solutes may be reduced greatly by ultrafiltration and chemical osmosis, relative to the flows predicted by advection and diffusion alone. In permeable materials, thermal diffusion may contribute to solute flows to a smaller, but still significant, extent.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 26: Symposium D – Scientific Basis for Nuclear Waste Management VII , 1983 , 1023
Copyright
Copyright © Materials Research Society 1984

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